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Bütünüyle Katı Hal PVC Membran Gümüş(I)–Seçici Elektrot ve Potansiyometrik Uygulamaları

Year 2024, Volume: 5 Issue: 2, 101 - 107, 28.11.2024

Oğuz Özbek

Abstract

Gümüş farklı alanlarda yaygın olarak kullanılmaktadır ve yüksek konsantrasyonlarda toksiktir. Bu çalışmada gümüş(I) iyonlarına seçici yeni bir PVC membran potansiyometrik elektrot geliştirildi. Yeni geliştirilen elektrot, 1,0×10-5–1,0×10-1 M konsantrasyon aralığında 53,0±3,6 mV/on katlık derişim yakın-Nernstian tepkiye ve 4,2×10-6 M’lık düşük bir tayin limitine sahiptir. Elektrot, 10 saniyeden kısa hızlı cevap zamanına sahiptir ve pH 3,0–8,0 aralığında pH değişikliklerinden etkilenmeden çalışabilmektedir. Son olarak önerilen yeni elektrot, su numunelerindeki gümüş(I) iyonlarını yüksek geri kazanımlarla tespit edebilmektedir.

Keywords

Gümüş(I) İyon seçici elektrotlar Potansiyometri Sensör

References

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  • Chen, X., & Schluesener, H. J. (2008). Nanosilver: a nanoproduct in medical application. Toxicology Letters, 176(1), 1-12.
  • Abu-Shawish, H. M., Saadeh, S. M., Dalloul, H. M., Najri, B., & Al Athamna, H. (2013). Modified carbon paste electrode for potentiometric determination of silver (I) ions in burning cream and radiological films. Sensors and Actuators B: Chemical, 182, 374-381.
  • Bianchin, J. N., Martendal, E., & Carasek, E. (2011). Determination of trace silver in water samples by online column preconcentration flame atomic absorption spectrometry using termite digestion product. Journal of Analytical Methods in Chemistry, 2011.
  • Valverde, F., Costas, M., Pena, F., Lavilla, I., & Bendicho, C. (2008). Determination of total silver and silver species in coastal seawater by inductively-coupled plasma mass spectrometry after batch sorption experiments with Chelex-100 resin. Chemical Speciation & Bioavailability, 20(4), 217-226.
  • Saha, R. K. (2016). Spectrophotometric micro determination of silver (I) using meloxicam as a new analytical reagent. Oriental Journal of Chemistry, 32(1), 499-507.
  • Verma, S., Sharma, A. K., & Shukla, S. K. (2023). Self-fuelled nickel oxide encapsulated sodium alginate-grafted-polypyrrole for potentiometric sensing of lead ions. Materials Science and Engineering: B, 293, 116469.
  • Özbek, O., Ugur, Ö. B., Ören, S., Gürdere, M. B., & Kocabas, S. (2024). New solid state contact potentiometric sensor based on a thiosemicarbazone derivative molecule for determination of copper (II) ions in environmental samples. Polyhedron, 116878.
  • Topcu, C. (2016). Highly selective direct determination of chlorate ions by using a newly developed potentiometric electrode based on modified smectite. Talanta, 161, 623-631.
  • Isildak, I., Attar, A., Demir, E., Kemer, B., & Aboul-Enein, H. Y. (2018). A novel all solid-state contact PVC-membrane beryllium-selective electrode based on 4-hydroxybenzo-15-crown-5 ether ionophore. Current Analytical Chemistry, 14(1), 43-48.
  • Cetin, A., Özbek, O., & Erol, A. (2023). Development of a potentiometric sensor for the determination of carbamazepine and its application in pharmaceutical formulations. Journal of Chemical Technology & Biotechnology, 98(4), 890-897.
  • Kamel, A. H., & Abd-Rabboh, H. S. (2024). Imprinted polymer/reduced graphene oxide-modified glassy carbon electrode-based highly sensitive potentiometric sensing module for imidacloprid detection. Microchemical Journal, 197, 109789.
  • Huang, M. R., Rao, X. W., Li, X. G., & Ding, Y. B. (2011). Lead ion-selective electrodes based on polyphenylenediamine as unique solid ionophores. Talanta, 85(3), 1575-1584.
  • Özbek, O. (2023). A potentiometric sensor for the determination of potassium in different baby follow–on milk, water, juice and pharmaceutical samples. Journal of Food Composition and Analysis, 115, 104937.
  • Wang, J., Liang, R., & Qin, W. (2024). Improvement of the selectivity of a molecularly imprinted polymer-based potentiometric sensor by using a specific functional monomer. Analytica Chimica Acta, 342412.
  • Özbek, O., & Altunoluk, O. C. (2023). Potentiometric determination of anti–epileptic drugs: A mini review. Sensors International, 4, 100224.
  • Özbek, O., Kalay, E., Berkel, C., Aslan, O. N., & Tokalı, F. S. (2024). Synthesis, characterization and sensor properties of a new sulfonyl hydrazone derivative molecule: potentiometric determination of Pb (II) ions. Chemical Papers, 1-13.
  • Özbek, O., & Ölcenoglu, A. (2023). The use of bis–thiadiazole and bis–oxadiazol derivatives as ionophores: a novel copper (II)–selective potentiometric electrodes. Microchemical Journal, 190, 108679.
  • Özbek, O. (2022). A novel potentiometric sensor for the determination of Pb (II) Ions based on a carbothioamide derivative in PVC matrix. Journal of the Turkish Chemical Society Section A: Chemistry, 9(3), 651-662.
  • Göver, T., Ertürün, H. E. K., Özel, A. D., Erdemir, S., & Canel, E. (2017). İyonofor olarak bir Kaliks [4] aren türevinin kullanıldığı iyodür-seçici PVC Membran elektrot. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 21(2), 437-443.
  • Buck, R. P., & Lindner, E. (1994). Recommendations for nomenclature of ionselective electrodes (IUPAC Recommendations 1994). Pure and Applied Chemistry, 66(12), 2527-2536.
  • Umezawa, Y., Bühlmann, P., Umezawa, K., Tohda, K., & Amemiya, S. (2000). Potentiometric selectivity coefficients of ion-selective electrodes. Part I. Inorganic cations (technical report). Pure and Applied Chemistry, 72(10), 1851-2082.
  • Sejmanović, D. M., Petković, B. B., Budimir, M. V., Sovilj, S. P., & Jovanović, V. M. (2011). Characterization of a Silver Modified PVCAc Electrode and Its Application as a Ag (I)‐Selective Potentiometric Sensor. Electroanalysis, 23(8), 1849-1855.
  • Chen, L., Ju, H., Zeng, X., He, X., & Zhang, Z. (2001). Silver ion-selective electrodes based on novel containing benzothiazolyl calix [4] arene. Analytica Chimica Acta, 437(2), 191-197.
  • Demirel, A., Doğan, A., Akkuş, G., Yılmaz, M., & Kılıç, E. (2006). Silver (I)‐Selective PVC Membrane Potentiometric Sensor Based on a Recently Synthesized Calix [4] arene. Electroanalysis 18(10), 1019-1027.
  • Mahajan, R. K., Kumar, M., Sharma, V., & Kaur, I. (2001). Silver (I) ion-selective membrane based on Schiff base–p-tert-butylcalix [4] arene. Analyst, 126(4), 505-507.
  • Masrournia, M., Zamani, H., Mohammedzadeh, H.,Seyedi, S. M., Ganjali, M. R., Eshghi, H., (2009). A silver(I) PVC-membrane sensor based on synthesized dilaktam crown ether. Journal of the Chilean Chemical Society, 54(1), 63-67.
  • Mazloum, M., Salavati Niassary, M., Mirhoseini Chahooki, S. H., & Amini, M. K. (2002). Silver‐Selective Coated‐Wire Electrode Based on Resorc [4] arene Neutral Carrier. Electroanalysis, 14(5), 376-381.
  • Mahajan, R. K., Kaur, I., Sharma, V., & Kumar, M. (2002). Sensor for silver (I) ion based on Schiff-base-p-tertbutylcalix [4] arene. Sensors, 2(10), 417-423.

Year 2024, Volume: 5 Issue: 2, 101 - 107, 28.11.2024

Oğuz Özbek

Abstract

References

  • Xu, K., Perez-Rafols, C., Cuartero, M., & Crespo, G. A. (2021). Electrochemical detection of trace silver. Electrochimica Acta, 374, 137929.
  • Chen, X., & Schluesener, H. J. (2008). Nanosilver: a nanoproduct in medical application. Toxicology Letters, 176(1), 1-12.
  • Abu-Shawish, H. M., Saadeh, S. M., Dalloul, H. M., Najri, B., & Al Athamna, H. (2013). Modified carbon paste electrode for potentiometric determination of silver (I) ions in burning cream and radiological films. Sensors and Actuators B: Chemical, 182, 374-381.
  • Bianchin, J. N., Martendal, E., & Carasek, E. (2011). Determination of trace silver in water samples by online column preconcentration flame atomic absorption spectrometry using termite digestion product. Journal of Analytical Methods in Chemistry, 2011.
  • Valverde, F., Costas, M., Pena, F., Lavilla, I., & Bendicho, C. (2008). Determination of total silver and silver species in coastal seawater by inductively-coupled plasma mass spectrometry after batch sorption experiments with Chelex-100 resin. Chemical Speciation & Bioavailability, 20(4), 217-226.
  • Saha, R. K. (2016). Spectrophotometric micro determination of silver (I) using meloxicam as a new analytical reagent. Oriental Journal of Chemistry, 32(1), 499-507.
  • Verma, S., Sharma, A. K., & Shukla, S. K. (2023). Self-fuelled nickel oxide encapsulated sodium alginate-grafted-polypyrrole for potentiometric sensing of lead ions. Materials Science and Engineering: B, 293, 116469.
  • Özbek, O., Ugur, Ö. B., Ören, S., Gürdere, M. B., & Kocabas, S. (2024). New solid state contact potentiometric sensor based on a thiosemicarbazone derivative molecule for determination of copper (II) ions in environmental samples. Polyhedron, 116878.
  • Topcu, C. (2016). Highly selective direct determination of chlorate ions by using a newly developed potentiometric electrode based on modified smectite. Talanta, 161, 623-631.
  • Isildak, I., Attar, A., Demir, E., Kemer, B., & Aboul-Enein, H. Y. (2018). A novel all solid-state contact PVC-membrane beryllium-selective electrode based on 4-hydroxybenzo-15-crown-5 ether ionophore. Current Analytical Chemistry, 14(1), 43-48.
  • Cetin, A., Özbek, O., & Erol, A. (2023). Development of a potentiometric sensor for the determination of carbamazepine and its application in pharmaceutical formulations. Journal of Chemical Technology & Biotechnology, 98(4), 890-897.
  • Kamel, A. H., & Abd-Rabboh, H. S. (2024). Imprinted polymer/reduced graphene oxide-modified glassy carbon electrode-based highly sensitive potentiometric sensing module for imidacloprid detection. Microchemical Journal, 197, 109789.
  • Huang, M. R., Rao, X. W., Li, X. G., & Ding, Y. B. (2011). Lead ion-selective electrodes based on polyphenylenediamine as unique solid ionophores. Talanta, 85(3), 1575-1584.
  • Özbek, O. (2023). A potentiometric sensor for the determination of potassium in different baby follow–on milk, water, juice and pharmaceutical samples. Journal of Food Composition and Analysis, 115, 104937.
  • Wang, J., Liang, R., & Qin, W. (2024). Improvement of the selectivity of a molecularly imprinted polymer-based potentiometric sensor by using a specific functional monomer. Analytica Chimica Acta, 342412.
  • Özbek, O., & Altunoluk, O. C. (2023). Potentiometric determination of anti–epileptic drugs: A mini review. Sensors International, 4, 100224.
  • Özbek, O., Kalay, E., Berkel, C., Aslan, O. N., & Tokalı, F. S. (2024). Synthesis, characterization and sensor properties of a new sulfonyl hydrazone derivative molecule: potentiometric determination of Pb (II) ions. Chemical Papers, 1-13.
  • Özbek, O., & Ölcenoglu, A. (2023). The use of bis–thiadiazole and bis–oxadiazol derivatives as ionophores: a novel copper (II)–selective potentiometric electrodes. Microchemical Journal, 190, 108679.
  • Özbek, O. (2022). A novel potentiometric sensor for the determination of Pb (II) Ions based on a carbothioamide derivative in PVC matrix. Journal of the Turkish Chemical Society Section A: Chemistry, 9(3), 651-662.
  • Göver, T., Ertürün, H. E. K., Özel, A. D., Erdemir, S., & Canel, E. (2017). İyonofor olarak bir Kaliks [4] aren türevinin kullanıldığı iyodür-seçici PVC Membran elektrot. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 21(2), 437-443.
  • Buck, R. P., & Lindner, E. (1994). Recommendations for nomenclature of ionselective electrodes (IUPAC Recommendations 1994). Pure and Applied Chemistry, 66(12), 2527-2536.
  • Umezawa, Y., Bühlmann, P., Umezawa, K., Tohda, K., & Amemiya, S. (2000). Potentiometric selectivity coefficients of ion-selective electrodes. Part I. Inorganic cations (technical report). Pure and Applied Chemistry, 72(10), 1851-2082.
  • Sejmanović, D. M., Petković, B. B., Budimir, M. V., Sovilj, S. P., & Jovanović, V. M. (2011). Characterization of a Silver Modified PVCAc Electrode and Its Application as a Ag (I)‐Selective Potentiometric Sensor. Electroanalysis, 23(8), 1849-1855.
  • Chen, L., Ju, H., Zeng, X., He, X., & Zhang, Z. (2001). Silver ion-selective electrodes based on novel containing benzothiazolyl calix [4] arene. Analytica Chimica Acta, 437(2), 191-197.
  • Demirel, A., Doğan, A., Akkuş, G., Yılmaz, M., & Kılıç, E. (2006). Silver (I)‐Selective PVC Membrane Potentiometric Sensor Based on a Recently Synthesized Calix [4] arene. Electroanalysis 18(10), 1019-1027.
  • Mahajan, R. K., Kumar, M., Sharma, V., & Kaur, I. (2001). Silver (I) ion-selective membrane based on Schiff base–p-tert-butylcalix [4] arene. Analyst, 126(4), 505-507.
  • Masrournia, M., Zamani, H., Mohammedzadeh, H.,Seyedi, S. M., Ganjali, M. R., Eshghi, H., (2009). A silver(I) PVC-membrane sensor based on synthesized dilaktam crown ether. Journal of the Chilean Chemical Society, 54(1), 63-67.
  • Mazloum, M., Salavati Niassary, M., Mirhoseini Chahooki, S. H., & Amini, M. K. (2002). Silver‐Selective Coated‐Wire Electrode Based on Resorc [4] arene Neutral Carrier. Electroanalysis, 14(5), 376-381.
  • Mahajan, R. K., Kaur, I., Sharma, V., & Kumar, M. (2002). Sensor for silver (I) ion based on Schiff-base-p-tertbutylcalix [4] arene. Sensors, 2(10), 417-423.
There are 29 citations in total.

Details

Primary Language Turkish
Subjects Sensor Technology
Journal Section Araştırma Makaleleri
Authors

Oğuz Özbek 0000-0001-5185-9681

Publication Date November 28, 2024
Submission Date April 11, 2024
Acceptance Date June 14, 2024
Published in Issue Year 2024 Volume: 5 Issue: 2

Cite

APA Özbek, O. (2024). Bütünüyle Katı Hal PVC Membran Gümüş(I)–Seçici Elektrot ve Potansiyometrik Uygulamaları. Gazi Üniversitesi Fen Fakültesi Dergisi, 5(2), 101-107.
AMA Özbek O. Bütünüyle Katı Hal PVC Membran Gümüş(I)–Seçici Elektrot ve Potansiyometrik Uygulamaları. GÜFFD. November 2024;5(2):101-107.
Chicago Özbek, Oğuz. “Bütünüyle Katı Hal PVC Membran Gümüş(I)–Seçici Elektrot Ve Potansiyometrik Uygulamaları”. Gazi Üniversitesi Fen Fakültesi Dergisi 5, no. 2 (November 2024): 101-7.
EndNote Özbek O (November 1, 2024) Bütünüyle Katı Hal PVC Membran Gümüş(I)–Seçici Elektrot ve Potansiyometrik Uygulamaları. Gazi Üniversitesi Fen Fakültesi Dergisi 5 2 101–107.
IEEE O. Özbek, “Bütünüyle Katı Hal PVC Membran Gümüş(I)–Seçici Elektrot ve Potansiyometrik Uygulamaları”, GÜFFD, vol. 5, no. 2, pp. 101–107, 2024.
ISNAD Özbek, Oğuz. “Bütünüyle Katı Hal PVC Membran Gümüş(I)–Seçici Elektrot Ve Potansiyometrik Uygulamaları”. Gazi Üniversitesi Fen Fakültesi Dergisi 5/2 (November 2024), 101-107.
JAMA Özbek O. Bütünüyle Katı Hal PVC Membran Gümüş(I)–Seçici Elektrot ve Potansiyometrik Uygulamaları. GÜFFD. 2024;5:101–107.
MLA Özbek, Oğuz. “Bütünüyle Katı Hal PVC Membran Gümüş(I)–Seçici Elektrot Ve Potansiyometrik Uygulamaları”. Gazi Üniversitesi Fen Fakültesi Dergisi, vol. 5, no. 2, 2024, pp. 101-7.
Vancouver Özbek O. Bütünüyle Katı Hal PVC Membran Gümüş(I)–Seçici Elektrot ve Potansiyometrik Uygulamaları. GÜFFD. 2024;5(2):101-7.