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The Effects of PANI Concentration on the Mechanical Properties of PP/PANI Composites

Year 2018, Volume: 18 Issue: 2, 426 - 433, 31.08.2018

Mehmet Kılıç Ümit Alkan Yaşar Karabul Hale Berber Yamak Orhan İçelli

Abstract

In this study, the effect of PANI additive with different concentrations (0.3-3.0 wt.%) on mechanical properties of Polypropylene/Polyaniline (PP/PANI) film composites have been investigated. The composites films obtained from the hot pressing technique have been characterized to determine their surface properties and structural morphology (SEM and FT-IR), thermal properties (TG). The effects of PANI additive on mechanical properties of polypropylene have been examined by tensile tests. In particular, tensile strength, Young's modulus and percentage strain at break of the composites have been tested. According to our results, it has been observed that the PANI additive in polypropylene had a significant impact on its mechanical properties. The tensile strength has been reached highest value in PP/0.6 wt.% PANI composites.

Keywords

Polypropylene Polyaniline Polymer composites Mechanical properties stress-strain

References

  • Abd Razak, S.I., Abdul Rahman, W.A.W., Hashim, S., Yahya, M.Y., 2013. Polyaniline and their Conductive Polymer Blends: A Short Review. Malaysian Journal of Fundamental and Applied Sciences, 9, 74–80.
  • Akinci, A., 2009. Mechanical and structural properties of polypropylene composites filled with graphite flakes. Archives of Material Science and Engineering, 35, 91–94.
  • Alkan, U., Özcanlı, Y., Alekberov, V., 2013. Effect of temperature and time on mechanical and electrical properties of HDPE/glass fiber composites. Fibers Polymers, 14, 115–120.
  • Ameli, A., Jung, P.U., Park, C.B., 2013. Electrical properties and electromagnetic interference shielding effectiveness of polypropylene/carbon fiber composite foams. Carbon, 60, 379–391.
  • Ates, M., 2013. A review study of (bio) sensor systems based on conducting polymers. Materials Science and Engineering C, 33, 1853–1859.
  • Bhadra, S., Khastgir, D., Singha, N.K., Lee, J.H., 2009. Progress in preparation, processing and applications of polyaniline. Progress in Polymer Science, 34, 783–810.
  • Boeva, Zh. A., Sergeyev, V.G., 2014. Polyaniline: Synthesis, Properties, and Application. Polymer Science Series C, 56, 144–153.
  • Byelov, D., Panine, P., De Jeu, W.H., 2007. Shear-Induced Smectic Order in Isotactic Polypropylene Revisited. Macromolecules, 40, 288–289.
  • Chen, X., Guo, Q., Mi, Y., 1998. Bamboo Fiber-Reinforced Polypropylene Composites: A Study of the Mechanical Properties. Journal of Applied Polymer Science, 69, 1891–1899.
  • Cho, S., Kim, M., Lee, J. S., Jang, J., 2015. Polypropylene/Polyaniline Nanofiber/Reduced Graphene Oxide Nanocomposite with Enhanced Electrical, Dielectric, and Ferroelectric Properties for a High Energy Density Capacitor. ACS Appl. Mater. Interfaces, 7, 22301–22314.
  • Chodak, I., Omastova, M., Pionteck, J., 2001. Relation between electrical and mechanical properties of conducting polymer composites. Journal of Applied Polymer Science, 82, 1903–1906.
  • Fekete, E., Hornsby, P.R., Jancar, J., Pukánszky, B., Rothon, R.N. 2003. Mineral Fillers in Thermoplastics I: Raw Materials and Processing. Springer.
  • Ghanbari, Kh., Mousavi, M.F., Shamsipur, M., 2006. Preparation of polyaniline nanofibers and their use as a cathode of aqueous rechargeable batteries. Electrochimica Acta, 52, 1514–1522.
  • Kim, J.S. and Kim, D.H., 2015. Compatibilizing effects of maleic anhydride-grafted-polypropylene (PP) on long Carbon fiber-reinforced PP composites. Journal of Thermoplastic Composite Materials, 28, 1599–1611.
  • Liang, J.-Z., Zhou, T.-Y., Zou, S.-Y., 2016. Non-isothermal crystallization properties of polypropylene composites filled with multi-walled carbon nanotubes. Polymer Testing, 55, 184–189.
  • Pickering K.L., Efendy, M.G.A., Le, T. M., 2016. A review of recent developments in natural fibre composites and their mechanical performance. Composites Part A: Applied Science and Manufacturing, 83, 98–112.
  • Piletsky, S., Piletska, E., Bossi, A., Turner, N., Turner A., 2003. Surface Functionalization of Porous Polypropylene Membranes with Polyaniline forProtein Immobilization. Biotechnology and Bioengineering, 82, 86-92.
  • Pukánszky, B., Voros, G., 1996. Stress distribution around inclusions, interaction, and mechanical properties of particulate‐filled composites. Polymer Composites, 17, 384–392.
  • Saleem, A., Frormann, L., Iqbal, A., 2007. Mechanical, Thermal and Electrical Resistivity Properties of Thermoplastic Composites Filled with Carbon Fibers and Carbon Particles. Journal of Polymer Research, 14, 121–127.
  • Samui, A.B., Patankar, A.S., Rangarajan, J., Deb, P.C., 2003. Study of polyaniline containing paint for corrosion prevention. Progress in Organic Coatings, 47, 1–7.
  • Schackletta, L.W., Han, C. C., Luly, M. H., 1993. Polyaniline Blends in Thermoplastics. Synthetic Metals, 55–57, 3532–3537.
  • Taipalus, R., Harmia, T., Friedrich, K., 1999. Short Fibre Reinforced PP/PANI-Complex Blends and their Mechanical and Electrical Properties. Applied Composite Materials, 6, 167–175.
  • Taipalus, R., Harmia, T., Friedrich, K., 2000. Influence of PANI-Complex on the Mechanical and Electrical Properties of Carbon Fiber Reinforced PoIypropyIene Composites. Polymer Composites, 21, 396–416.
  • Wang, X., Liu, J., Zhang, S., Chimin D., 2012. Flexible conductive polyaniline-silica/polypropylene composite membrane. Synthetic Metals, 162, 1459–1463.
  • Wen-Zhi, Z., Xian-Wen, K., Shou-Feng, J., Jin-Gao, S., Dong-Sheng, Y., Bin, F., 2006. Electrochemical characteristics and catalytic activity of polyaniline doped with ferrocene perchlorate. Journal of Applied Polymer Science, 102, 5633–5639.
  • Wu, C. L., Zhang, M. Q., Rong M. Z., Friedrich K., 2002. Tensile performance improvement of low nanoparticles filled-polypropylene composites. Composites Science and Technology, 62, 1327–1340.
  • Yang, J., Zhao, C., Cui, D., Hou, J., Wan, M., Xu, M., 1995. Polyaniline/polypropylene film composites with high electric conductivity and good mechanical properties. Journal of Applied Polymer Science, 56, 831–836.

Year 2018, Volume: 18 Issue: 2, 426 - 433, 31.08.2018

Mehmet Kılıç Ümit Alkan Yaşar Karabul Hale Berber Yamak Orhan İçelli

Abstract

References

  • Abd Razak, S.I., Abdul Rahman, W.A.W., Hashim, S., Yahya, M.Y., 2013. Polyaniline and their Conductive Polymer Blends: A Short Review. Malaysian Journal of Fundamental and Applied Sciences, 9, 74–80.
  • Akinci, A., 2009. Mechanical and structural properties of polypropylene composites filled with graphite flakes. Archives of Material Science and Engineering, 35, 91–94.
  • Alkan, U., Özcanlı, Y., Alekberov, V., 2013. Effect of temperature and time on mechanical and electrical properties of HDPE/glass fiber composites. Fibers Polymers, 14, 115–120.
  • Ameli, A., Jung, P.U., Park, C.B., 2013. Electrical properties and electromagnetic interference shielding effectiveness of polypropylene/carbon fiber composite foams. Carbon, 60, 379–391.
  • Ates, M., 2013. A review study of (bio) sensor systems based on conducting polymers. Materials Science and Engineering C, 33, 1853–1859.
  • Bhadra, S., Khastgir, D., Singha, N.K., Lee, J.H., 2009. Progress in preparation, processing and applications of polyaniline. Progress in Polymer Science, 34, 783–810.
  • Boeva, Zh. A., Sergeyev, V.G., 2014. Polyaniline: Synthesis, Properties, and Application. Polymer Science Series C, 56, 144–153.
  • Byelov, D., Panine, P., De Jeu, W.H., 2007. Shear-Induced Smectic Order in Isotactic Polypropylene Revisited. Macromolecules, 40, 288–289.
  • Chen, X., Guo, Q., Mi, Y., 1998. Bamboo Fiber-Reinforced Polypropylene Composites: A Study of the Mechanical Properties. Journal of Applied Polymer Science, 69, 1891–1899.
  • Cho, S., Kim, M., Lee, J. S., Jang, J., 2015. Polypropylene/Polyaniline Nanofiber/Reduced Graphene Oxide Nanocomposite with Enhanced Electrical, Dielectric, and Ferroelectric Properties for a High Energy Density Capacitor. ACS Appl. Mater. Interfaces, 7, 22301–22314.
  • Chodak, I., Omastova, M., Pionteck, J., 2001. Relation between electrical and mechanical properties of conducting polymer composites. Journal of Applied Polymer Science, 82, 1903–1906.
  • Fekete, E., Hornsby, P.R., Jancar, J., Pukánszky, B., Rothon, R.N. 2003. Mineral Fillers in Thermoplastics I: Raw Materials and Processing. Springer.
  • Ghanbari, Kh., Mousavi, M.F., Shamsipur, M., 2006. Preparation of polyaniline nanofibers and their use as a cathode of aqueous rechargeable batteries. Electrochimica Acta, 52, 1514–1522.
  • Kim, J.S. and Kim, D.H., 2015. Compatibilizing effects of maleic anhydride-grafted-polypropylene (PP) on long Carbon fiber-reinforced PP composites. Journal of Thermoplastic Composite Materials, 28, 1599–1611.
  • Liang, J.-Z., Zhou, T.-Y., Zou, S.-Y., 2016. Non-isothermal crystallization properties of polypropylene composites filled with multi-walled carbon nanotubes. Polymer Testing, 55, 184–189.
  • Pickering K.L., Efendy, M.G.A., Le, T. M., 2016. A review of recent developments in natural fibre composites and their mechanical performance. Composites Part A: Applied Science and Manufacturing, 83, 98–112.
  • Piletsky, S., Piletska, E., Bossi, A., Turner, N., Turner A., 2003. Surface Functionalization of Porous Polypropylene Membranes with Polyaniline forProtein Immobilization. Biotechnology and Bioengineering, 82, 86-92.
  • Pukánszky, B., Voros, G., 1996. Stress distribution around inclusions, interaction, and mechanical properties of particulate‐filled composites. Polymer Composites, 17, 384–392.
  • Saleem, A., Frormann, L., Iqbal, A., 2007. Mechanical, Thermal and Electrical Resistivity Properties of Thermoplastic Composites Filled with Carbon Fibers and Carbon Particles. Journal of Polymer Research, 14, 121–127.
  • Samui, A.B., Patankar, A.S., Rangarajan, J., Deb, P.C., 2003. Study of polyaniline containing paint for corrosion prevention. Progress in Organic Coatings, 47, 1–7.
  • Schackletta, L.W., Han, C. C., Luly, M. H., 1993. Polyaniline Blends in Thermoplastics. Synthetic Metals, 55–57, 3532–3537.
  • Taipalus, R., Harmia, T., Friedrich, K., 1999. Short Fibre Reinforced PP/PANI-Complex Blends and their Mechanical and Electrical Properties. Applied Composite Materials, 6, 167–175.
  • Taipalus, R., Harmia, T., Friedrich, K., 2000. Influence of PANI-Complex on the Mechanical and Electrical Properties of Carbon Fiber Reinforced PoIypropyIene Composites. Polymer Composites, 21, 396–416.
  • Wang, X., Liu, J., Zhang, S., Chimin D., 2012. Flexible conductive polyaniline-silica/polypropylene composite membrane. Synthetic Metals, 162, 1459–1463.
  • Wen-Zhi, Z., Xian-Wen, K., Shou-Feng, J., Jin-Gao, S., Dong-Sheng, Y., Bin, F., 2006. Electrochemical characteristics and catalytic activity of polyaniline doped with ferrocene perchlorate. Journal of Applied Polymer Science, 102, 5633–5639.
  • Wu, C. L., Zhang, M. Q., Rong M. Z., Friedrich K., 2002. Tensile performance improvement of low nanoparticles filled-polypropylene composites. Composites Science and Technology, 62, 1327–1340.
  • Yang, J., Zhao, C., Cui, D., Hou, J., Wan, M., Xu, M., 1995. Polyaniline/polypropylene film composites with high electric conductivity and good mechanical properties. Journal of Applied Polymer Science, 56, 831–836.
There are 27 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Mehmet Kılıç

Ümit Alkan

Yaşar Karabul

Hale Berber Yamak

Orhan İçelli

Publication Date August 31, 2018
Submission Date June 30, 2017
Published in Issue Year 2018 Volume: 18 Issue: 2

Cite

APA Kılıç, M., Alkan, Ü., Karabul, Y., Berber Yamak, H., et al. (2018). The Effects of PANI Concentration on the Mechanical Properties of PP/PANI Composites. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 18(2), 426-433.
AMA Kılıç M, Alkan Ü, Karabul Y, Berber Yamak H, İçelli O. The Effects of PANI Concentration on the Mechanical Properties of PP/PANI Composites. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. August 2018;18(2):426-433.
Chicago Kılıç, Mehmet, Ümit Alkan, Yaşar Karabul, Hale Berber Yamak, and Orhan İçelli. “The Effects of PANI Concentration on the Mechanical Properties of PP/PANI Composites”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 18, no. 2 (August 2018): 426-33.
EndNote Kılıç M, Alkan Ü, Karabul Y, Berber Yamak H, İçelli O (August 1, 2018) The Effects of PANI Concentration on the Mechanical Properties of PP/PANI Composites. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 18 2 426–433.
IEEE M. Kılıç, Ü. Alkan, Y. Karabul, H. Berber Yamak, and O. İçelli, “The Effects of PANI Concentration on the Mechanical Properties of PP/PANI Composites”, Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 18, no. 2, pp. 426–433, 2018.
ISNAD Kılıç, Mehmet et al. “The Effects of PANI Concentration on the Mechanical Properties of PP/PANI Composites”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 18/2 (August 2018), 426-433.
JAMA Kılıç M, Alkan Ü, Karabul Y, Berber Yamak H, İçelli O. The Effects of PANI Concentration on the Mechanical Properties of PP/PANI Composites. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2018;18:426–433.
MLA Kılıç, Mehmet et al. “The Effects of PANI Concentration on the Mechanical Properties of PP/PANI Composites”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 18, no. 2, 2018, pp. 426-33.
Vancouver Kılıç M, Alkan Ü, Karabul Y, Berber Yamak H, İçelli O. The Effects of PANI Concentration on the Mechanical Properties of PP/PANI Composites. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2018;18(2):426-33.


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