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DETERMINATION OF THE STOICHIOMETRIES OF THE NİCKEL COMPLEXES WITH CARBOXYLIC ACIDS BY EXTRACTION

Year 1987, Volume: 33 , 16 - 23, 01.01.1987
https://doi.org/10.1501/Commub_0000000476

Abstract

In this study the extraction of nickel, from aqueous NiCI2 and NiSO4 Solutions with octa- noic, decanoic and lauric acid dissolved in kerosen was investigated within the pH range of 6-8. The probable compositions of the complex structure was determined by statistical method.
The calculations suggest that with 0.5 M octanoic acid, 0.5 and 1 M decanoic acid dimeric complexes are formed. The number of solvating acid molecules per metal ion 0,1 or 2.
With 1 M octanoic acid it forms monomeric and dimeric complexes. The number of sol-vating acid molecules per metal ion is found to be 0,1 or 2.
Monomeric complexc3 are formed with 0.5 M lauric acid. The number of solvating acid molecules per metal ion is 0 or 1.

References

  • Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
Year 1987, Volume: 33 , 16 - 23, 01.01.1987
https://doi.org/10.1501/Commub_0000000476

Abstract

References

  • Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
There are 1 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Article
Authors

Necla Gündüz

Publication Date January 1, 1987
Published in Issue Year 1987 Volume: 33

Cite

Vancouver Gündüz N. DETERMINATION OF THE STOICHIOMETRIES OF THE NİCKEL COMPLEXES WITH CARBOXYLIC ACIDS BY EXTRACTION. Commun. Fac. Sci. Univ. Ank. Ser. B. 1987;33:16-23.

Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering

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