Research Article
Year 2020,
Volume: 6 Issue: 1, 37 - 48, 12.01.2020
Abstract
The objective of this study is to evaluate the performance of pyrolysis-treated
rice straw (PPS) in the removal of methylene blue (MB) from aqueous solution.
Batch studies were performed to evaluate the influences of various experimental
parameters like pH (4, 5.9 (natural pH), 7, 9 and 11), initial dye
concentration (5, 10, 15, and 20 mg/L), and contact time (0, 1, 5, 15, 30, 60,
90, and 120 min) at constant temperature (20 oC) and adsorbent dose
(1 g/L). Also; the effect of ionic strength with the salt addition at different
doses (500, 1000, 1500, 2000, and 2500 mg/L NaCl) was evaluated on the color
removal efficiency from the dye solution. It was observed that the dye uptake
by PPS was slightly decrease (from 8.5 mg/g to about 8.2 mg/g for qe values)
when the pH of dye solution was increased from 4 to 11 and the best removal
efficiency was obtained at the natural pH (5.9). Uptakes of dye were rapid and
the adsorption increased with increasing contact time in all experiments.
Methylene Blue removal efficiency increased slightly with increasing ionic
strength. While the removal efficiency was 91 % at 2000 mg/L NaCl application,
decreased to 87% at 2500 mg/L NaCl. According to the R2 values for
the adsorption of MB on PPS, Langmuir model yields fit better than the
Freundlich model. The maximum adsorption capacity of PPS adsorbent for MB dye
was 12.5 mg/g. The kinetic experimental data fitted the pseudo-first-order
model for PPS (R2=0.9952).
References
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- Aktaş T., Dalmış İ.S., Tuğ S., Dalmış F., Kayişoğlu B., (2017), Çeltik Saplarının Gazlaştırılması Amacıyla Laboratuvar Tipi Bir Gazlaştırıcının Geliştirilmesi ve Denenmesi, Tekirdağ Ziraat Fakültesi Dergisi, 14(02), 119-128.
- Alaya M., Hourieh M., Youssef A., El-Sejarah F., (1999), Adsorption properties of activated carbons prepared from olive stones by chemical and physical activation, Adsorption Sci. Technol., 18, 27–42.
- Auta M., Hameed B.H., (2012), Modified Mesoporous Clay Adsorbent for Adsorption Isotherm and Kinetics of Methylene Blue, Chem. Eng. J., 198-199, 219-227. Aydın H., Bulut Y., Yerlikaya C., (2008), Removal og Copper (II) from Aqueous Solution by Adsorption onto Low-Cost Adsorbents, J. Environ. Manage., 87, 37–45.
- Aygun A., Yenisoy-Karakas S., Duman I., (2003), Production of Granular Activated Carbon from Fruit Stones and Nutshells and Evaluation of Their Physical, Chemical and Adsorption Properties, Microporous Mesoporous Mater., 66, 189–195.
- Ayoob S., Gupta A.K., Bhakat P.B., Bhat V.T., (2008), Investigations on the Kinetics and Mechanisms of Sorptive Removal of Fluoride from Water Using Alumina Cement Granules, Chem. Eng. J., 140, 6–14.
- Cheng M., Zeng G., Huang D., Lai C., Liu Y., Zhang C., Wang R., Qin L., Xue W., Song B., Ye S., Yi H., (2018), High adsorption of methylene blue by salicylic acid–methanol modified steel converter slag and evaluation of its mechanism, Journal of Colloid and Interface Science, 515, 232-239.
- Claoston N., Samsuri A.W., Ahmad Husni M.H., Mohd Amran M.S., (2014), Effects of pyrolysis temperature on the physicochemical properties of empty fruit bunch and rice husk biochars, Waste Management & Research, 32(4), 331 –339.
- Çaylak E., (2007), Ucuz adsorban kullanımıyla sulardan Cr(VI), fenol ve boyar maddelerin uzaklaştırılması, Ege Üniversitesi Fen Bilimleri Enstitüsü, Yüksek Lisans Tezi, İzmir.
- Dahri M.K., Kooh M.R.R., Linda B.L., Lim L.B.L., (2014), Water Remediation Using Low Cost Adsorbent WalnutShell for Removal of Malachite Green: Equilibrium, Kinetics, Thermodynamic and Regeneration Studies, J. Environ. Chem. Eng., 2, 1434-1444.
- Demiral İ., Çemrek Kul Ş., (2014), Pyrolysis of apricot kernel shell in a fixed-bed reactor: Characterization of bio-oil and char, Journal of Analytical and Applied Pyrolysis, 107, 17-24.
- Dincer A.R., Gunes Y., Karakaya N., Gunes E., (2007), Comparison of Activated Carbon and Bottom Ash for Removal of Reactive Dye from Aqueous Solution, Bioresour. Technol., 98, 834–839.
- Elekçioğlu İ.H., Tülek A., (2009), Çeltik Beyaz Uç Nematodu (Aphelenchoides besseyi Christie pv.oryzae Aphelenchida: Aphelenchoidae), 1. Çeltik Sempozyumu, Tekirdağ, ss.39-48.
- El-Halwany M.M., (2010), Study of adsorption isotherms and kinetic models for Methylene Blue adsorption on activated carbon developed from Egyptian rice hull (Part II), Desalination, 250(1), 208–213.
- Foo K. Y., Hameed B. H., (2009), Utilization of rice husk ash as novel adsorbent: a judicious recycling of the colloidal agricultural waste, Advances in Colloid and Interface Science, 152(1-2), 39–47.
- Gupta S.S., Bhattacharyya K., (2011), Kinetics of Adsorption of Metal Ions on Inorganic Materials: A review, Adv. Colloid Interface Sci., 162, 39–58.
- Hameed B.H., El-Khaiary M.I., (2008), Kinetics and equilibrium studies of malachite green adsorption on rice straw-derived char, Journal of Hazardous Materials, 153, 701-708.
- Hameed B.H., El-Khaiary M.I., (2008), Batch Removal of Malachite Green from Aqueous Solutions by Adsorption on Oil Palm Trunk Fibre: Equilibrium Isotherms and Kinetic Studies, Journal of Hazardous Materials, 154, 237–244.
- Huang Y.H., Hsueh C.L., Cheng H.P., Su L.C., Chen C.Y., (2007), Thermodynamics and Kinetics of Adsorption of Cu(II) onto Waste Iron Oxide, J. Hazard. Mater., 144, 406–411.
- Jain C.K., Kumar A., Izazy H., (2009), Color Removal from Paper Mill Effluent Through Adsorption Technology, Environ Monit Assess., 149, 343–348.
- Kalderis D., Koutoulakis D., Paraskeva P., Diamadopoulos E., Otal E., Valle J. O., Fern ́andez-Pereira C., (2008), Adsorption of polluting substances on activated carbons prepared from rice husk and sugarcane bagasse, Chemical Engineering Journal, 144 (1), 42–50.
- Kaykıoğlu G., (2016), Kolemanit ve Üleksit Atığı ile Sulu Çözeltilerden Metilen Mavisi Giderimi: Kinetik ve İzoterm Değerlendirmesi, CBU J. of Sci., 12(3), 499-509.
- Kaykioğlu G., Güneş, E., (2016) Kinetic and Equilibrium Study of Methylene Blue Adsorption Using H2SO4-activated Rice Husk Ash, Desalination and Water Treatment, 57, 7085–7097.
- Li Y., Du Q., Liu T., Peng X., Wang J., Sun J., Wang Y., Wu S., Wang Z., Xia Y., Xia L., (2013), Comparative Study of Methylene Blue Dye Adsorption onto Activated Carbon, Graphene Oxide, and Carbon Nanotubes, Chemical Engineering Research and Design., 91, 361–368.
- Li Y., Du Q., Liu T., Sun J., Wang Y., Wu S., Wang Z., Xia Y., Xia L., (2013), Methylene Blue Adsorption on Graphene Oxide/Calcium Alginate Composites, Carbohydrate Polymers., 95, 501– 507.
- Mane V.S., Mall I.D.,Srivastava V.C., (2007), Kinetic and Equilibrium Isotherm Studies for the Adsorptive Removal ofBrilliant Green Dye from Aqueous Solution by Rice Husk Ash, J. Environ. Manage., 84, 390–400.
- McKay G., Blair H., Gardiner J.R., (1989), The Adsorption of Dyes onto Chitin in Fixed Bed Column and Batch Adsorbers, J. Appl. Polym. Sci., 28, 1499–1544.
- Mouni L., Belkhiri L., Bollinger J.-C., Bouzaza A., Assadi A., Tirri A., Dahmoune F., Madani K., Remini H., (2018), Removal of Methylene Blue from aqueous solutions by adsorption on Kaolin: Kinetic and equilibrium studies, Applied Clay Science, 153, 38-45.
- Naiya T.K., Bhattacharyaa A.K., Mandal S., Das S.K., (2009), The Sorption of Lead(II) Ions on Rice Husk Ash, J. Hazard. Mater., 163, 1254–1264.
- Panneerselvam P., Morad N., Tan K. A., (2011), Magnetic nanoparticle (F3O4) impregnated onto teawaste for the removal of nickel(II) from aqueous solution, Journal of Hazardous Materials, 186(1), 160–168.
- Salehi R., Arami M., Mahmoodi N. M., Bahrami H., Khorramfar S., (2010), Novel biocompatible composite (Chitosanzinc oxide nanoparticle): preparation, characterization and dye adsorption properties, Colloids and Surfaces B: Biointerfaces, 80(1), 86–93.
- Suman S., Gautam S., (2017), Pyrolysis of coconut husk biomass: Analysis of its biochar properties Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 39(8), 761–767.
- Sürek H., Beşer N., Kaya R., (2007), Çeltikte Üstten Biçmenin Dane Verimi ve Bazı Agronomik Karakterlere Etkisi, Türkiye VII. Tarla Bitkileri Kongresi, 25-27 Haziran, Erzurum.
- Xu R.K., Xiao S.C., Yuan J.-H., Zhao A.Z., (2011), Adsorption of methyl violet from aqueous solutions by the biochars derived from crop residues, Bioresour. Technol., 102 (22), 10293-10298.
- Wang Y., Zeng L., Ren X., Song H., Wang A., (2010), Removal of Methyl Violet from aqueous solutions using poly (acrylic acid-co-acrylamide)/attapulgite composite, Journal of Environmental Sciences, 22(1), 7–14.
- Wu Z., Zhong H., Yuan X., Wang H., Wang L., Chen X., Zeng G., Wu Y., (2014), Adsorptive removal of methylene blue by rhamnolipid-functionalized graphene oxide from Wastewater, Water Research, 67, 330-344.
- Yang Y., Lin X., Wei B., Zhao Y., Wang J., (2013), Evaluation of adsorption potential of bamboo biochar for metal-complex dye: equilibrium, kinetics and artificial neural network modeling, Int. J. Environ. Sci. Technol., 11:1093-1100.
- Zhang G., Sun Y., Shi Y., Jia Y., Xu Y., Zhao P., Zhang Y., (2016), Characteristic and kinetics of corn stalk pyrolysis in a high pressure reactor and steam gasification of its char, Journal of Analytical and Applied Pyrolysis, 122, 249–257.
Year 2020,
Volume: 6 Issue: 1, 37 - 48, 12.01.2020
Abstract
Bu
çalışmanın amacı, piroliz uygulanmış pirinç sapları ile (PPS) sulu
çözeltilerden metilen mavisi (MB) giderim performansını değerlendirmektir. pH
(4, 5.9 (doğal pH), 7, 9 ve 11), başlangıç boya konsantrasyonu (5, 10, 15 ve 20
mg / L) ve temas süresi (0, 1, 5, 15, 30, 60, 90 ve 120 dakika) gibi çeşitli
deneysel parametrelerin etkisini değerlendirmek için sabit sıcaklıkta (20 oC)
ve sabit adsorban dozunda (1 g/L) kesikli çalışmalar yapılmıştır. Ayrıca;
farklı dozlarda (500, 1000, 1500, 2000 ve 2500 mg/L NaCl) tuz ilavesiyle iyonik
şiddetin boya çözeltisinden renk giderim verimi üzerine etkisi
değerlendirilmiştir. Boya çözeltisinin pH değerinin 4’ten 11’e yükseltilmesiyle
PPS tarafından boya tutulumunun bir miktar azaldığı (qe değerleri için 8.5 mg/g’dan
yaklaşık 8.2 mg/g’a) ve en iyi giderme veriminin doğal pH’ta elde edildiği
gözlenmiştir. Bütün deneylerde boya tutulumu hızlı
olmakta ve artan temas süresi ile birlikte adsorpsiyon artmaktadır. Metilen mavisi
giderim verimi artan iyonik şiddet ile birlikte hafif artış göstermiştir.
2000 mg/L NaCl uygulamasında %91 giderme verimi elde edilirken, 2500 mg/L
NaCl uygulamasında giderme verimi % 87’e düşmüştür. PPS ile MB adsorpsiyonunda
R2 değerleri dikkate alındığında Freundlich modeline göre Langmuir
modelinin daha uyumlu olduğu belirlenmiştir. MB boyarmaddesi için PPS
adsorbanının maksimum adsorpsiyon kapasitesi 12.5 mg/g’dır. PPS için deneysel
kinetik veriler yalancı birinci derece modele uyumludur (R2=0.9952).
References
- Akçay T., (2014), Trakya bölgesinde çeltik sapının biyokütle potansiyeli ve enerji değerlerinin saptanması, Namık Kemal Üniversitesi, Fen Bilimleri Enstitüsü, Yüksek Lisans Tezi, Tekirdağ.
- Aktaş T., Dalmış İ.S., Tuğ S., Dalmış F., Kayişoğlu B., (2017), Çeltik Saplarının Gazlaştırılması Amacıyla Laboratuvar Tipi Bir Gazlaştırıcının Geliştirilmesi ve Denenmesi, Tekirdağ Ziraat Fakültesi Dergisi, 14(02), 119-128.
- Alaya M., Hourieh M., Youssef A., El-Sejarah F., (1999), Adsorption properties of activated carbons prepared from olive stones by chemical and physical activation, Adsorption Sci. Technol., 18, 27–42.
- Auta M., Hameed B.H., (2012), Modified Mesoporous Clay Adsorbent for Adsorption Isotherm and Kinetics of Methylene Blue, Chem. Eng. J., 198-199, 219-227. Aydın H., Bulut Y., Yerlikaya C., (2008), Removal og Copper (II) from Aqueous Solution by Adsorption onto Low-Cost Adsorbents, J. Environ. Manage., 87, 37–45.
- Aygun A., Yenisoy-Karakas S., Duman I., (2003), Production of Granular Activated Carbon from Fruit Stones and Nutshells and Evaluation of Their Physical, Chemical and Adsorption Properties, Microporous Mesoporous Mater., 66, 189–195.
- Ayoob S., Gupta A.K., Bhakat P.B., Bhat V.T., (2008), Investigations on the Kinetics and Mechanisms of Sorptive Removal of Fluoride from Water Using Alumina Cement Granules, Chem. Eng. J., 140, 6–14.
- Cheng M., Zeng G., Huang D., Lai C., Liu Y., Zhang C., Wang R., Qin L., Xue W., Song B., Ye S., Yi H., (2018), High adsorption of methylene blue by salicylic acid–methanol modified steel converter slag and evaluation of its mechanism, Journal of Colloid and Interface Science, 515, 232-239.
- Claoston N., Samsuri A.W., Ahmad Husni M.H., Mohd Amran M.S., (2014), Effects of pyrolysis temperature on the physicochemical properties of empty fruit bunch and rice husk biochars, Waste Management & Research, 32(4), 331 –339.
- Çaylak E., (2007), Ucuz adsorban kullanımıyla sulardan Cr(VI), fenol ve boyar maddelerin uzaklaştırılması, Ege Üniversitesi Fen Bilimleri Enstitüsü, Yüksek Lisans Tezi, İzmir.
- Dahri M.K., Kooh M.R.R., Linda B.L., Lim L.B.L., (2014), Water Remediation Using Low Cost Adsorbent WalnutShell for Removal of Malachite Green: Equilibrium, Kinetics, Thermodynamic and Regeneration Studies, J. Environ. Chem. Eng., 2, 1434-1444.
- Demiral İ., Çemrek Kul Ş., (2014), Pyrolysis of apricot kernel shell in a fixed-bed reactor: Characterization of bio-oil and char, Journal of Analytical and Applied Pyrolysis, 107, 17-24.
- Dincer A.R., Gunes Y., Karakaya N., Gunes E., (2007), Comparison of Activated Carbon and Bottom Ash for Removal of Reactive Dye from Aqueous Solution, Bioresour. Technol., 98, 834–839.
- Elekçioğlu İ.H., Tülek A., (2009), Çeltik Beyaz Uç Nematodu (Aphelenchoides besseyi Christie pv.oryzae Aphelenchida: Aphelenchoidae), 1. Çeltik Sempozyumu, Tekirdağ, ss.39-48.
- El-Halwany M.M., (2010), Study of adsorption isotherms and kinetic models for Methylene Blue adsorption on activated carbon developed from Egyptian rice hull (Part II), Desalination, 250(1), 208–213.
- Foo K. Y., Hameed B. H., (2009), Utilization of rice husk ash as novel adsorbent: a judicious recycling of the colloidal agricultural waste, Advances in Colloid and Interface Science, 152(1-2), 39–47.
- Gupta S.S., Bhattacharyya K., (2011), Kinetics of Adsorption of Metal Ions on Inorganic Materials: A review, Adv. Colloid Interface Sci., 162, 39–58.
- Hameed B.H., El-Khaiary M.I., (2008), Kinetics and equilibrium studies of malachite green adsorption on rice straw-derived char, Journal of Hazardous Materials, 153, 701-708.
- Hameed B.H., El-Khaiary M.I., (2008), Batch Removal of Malachite Green from Aqueous Solutions by Adsorption on Oil Palm Trunk Fibre: Equilibrium Isotherms and Kinetic Studies, Journal of Hazardous Materials, 154, 237–244.
- Huang Y.H., Hsueh C.L., Cheng H.P., Su L.C., Chen C.Y., (2007), Thermodynamics and Kinetics of Adsorption of Cu(II) onto Waste Iron Oxide, J. Hazard. Mater., 144, 406–411.
- Jain C.K., Kumar A., Izazy H., (2009), Color Removal from Paper Mill Effluent Through Adsorption Technology, Environ Monit Assess., 149, 343–348.
- Kalderis D., Koutoulakis D., Paraskeva P., Diamadopoulos E., Otal E., Valle J. O., Fern ́andez-Pereira C., (2008), Adsorption of polluting substances on activated carbons prepared from rice husk and sugarcane bagasse, Chemical Engineering Journal, 144 (1), 42–50.
- Kaykıoğlu G., (2016), Kolemanit ve Üleksit Atığı ile Sulu Çözeltilerden Metilen Mavisi Giderimi: Kinetik ve İzoterm Değerlendirmesi, CBU J. of Sci., 12(3), 499-509.
- Kaykioğlu G., Güneş, E., (2016) Kinetic and Equilibrium Study of Methylene Blue Adsorption Using H2SO4-activated Rice Husk Ash, Desalination and Water Treatment, 57, 7085–7097.
- Li Y., Du Q., Liu T., Peng X., Wang J., Sun J., Wang Y., Wu S., Wang Z., Xia Y., Xia L., (2013), Comparative Study of Methylene Blue Dye Adsorption onto Activated Carbon, Graphene Oxide, and Carbon Nanotubes, Chemical Engineering Research and Design., 91, 361–368.
- Li Y., Du Q., Liu T., Sun J., Wang Y., Wu S., Wang Z., Xia Y., Xia L., (2013), Methylene Blue Adsorption on Graphene Oxide/Calcium Alginate Composites, Carbohydrate Polymers., 95, 501– 507.
- Mane V.S., Mall I.D.,Srivastava V.C., (2007), Kinetic and Equilibrium Isotherm Studies for the Adsorptive Removal ofBrilliant Green Dye from Aqueous Solution by Rice Husk Ash, J. Environ. Manage., 84, 390–400.
- McKay G., Blair H., Gardiner J.R., (1989), The Adsorption of Dyes onto Chitin in Fixed Bed Column and Batch Adsorbers, J. Appl. Polym. Sci., 28, 1499–1544.
- Mouni L., Belkhiri L., Bollinger J.-C., Bouzaza A., Assadi A., Tirri A., Dahmoune F., Madani K., Remini H., (2018), Removal of Methylene Blue from aqueous solutions by adsorption on Kaolin: Kinetic and equilibrium studies, Applied Clay Science, 153, 38-45.
- Naiya T.K., Bhattacharyaa A.K., Mandal S., Das S.K., (2009), The Sorption of Lead(II) Ions on Rice Husk Ash, J. Hazard. Mater., 163, 1254–1264.
- Panneerselvam P., Morad N., Tan K. A., (2011), Magnetic nanoparticle (F3O4) impregnated onto teawaste for the removal of nickel(II) from aqueous solution, Journal of Hazardous Materials, 186(1), 160–168.
- Salehi R., Arami M., Mahmoodi N. M., Bahrami H., Khorramfar S., (2010), Novel biocompatible composite (Chitosanzinc oxide nanoparticle): preparation, characterization and dye adsorption properties, Colloids and Surfaces B: Biointerfaces, 80(1), 86–93.
- Suman S., Gautam S., (2017), Pyrolysis of coconut husk biomass: Analysis of its biochar properties Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 39(8), 761–767.
- Sürek H., Beşer N., Kaya R., (2007), Çeltikte Üstten Biçmenin Dane Verimi ve Bazı Agronomik Karakterlere Etkisi, Türkiye VII. Tarla Bitkileri Kongresi, 25-27 Haziran, Erzurum.
- Xu R.K., Xiao S.C., Yuan J.-H., Zhao A.Z., (2011), Adsorption of methyl violet from aqueous solutions by the biochars derived from crop residues, Bioresour. Technol., 102 (22), 10293-10298.
- Wang Y., Zeng L., Ren X., Song H., Wang A., (2010), Removal of Methyl Violet from aqueous solutions using poly (acrylic acid-co-acrylamide)/attapulgite composite, Journal of Environmental Sciences, 22(1), 7–14.
- Wu Z., Zhong H., Yuan X., Wang H., Wang L., Chen X., Zeng G., Wu Y., (2014), Adsorptive removal of methylene blue by rhamnolipid-functionalized graphene oxide from Wastewater, Water Research, 67, 330-344.
- Yang Y., Lin X., Wei B., Zhao Y., Wang J., (2013), Evaluation of adsorption potential of bamboo biochar for metal-complex dye: equilibrium, kinetics and artificial neural network modeling, Int. J. Environ. Sci. Technol., 11:1093-1100.
- Zhang G., Sun Y., Shi Y., Jia Y., Xu Y., Zhao P., Zhang Y., (2016), Characteristic and kinetics of corn stalk pyrolysis in a high pressure reactor and steam gasification of its char, Journal of Analytical and Applied Pyrolysis, 122, 249–257.
There are 38 citations in total.
Details
| Primary Language | Turkish |
|---|---|
| Subjects | Environmental Engineering |
| Journal Section | Research Articles |
| Authors | |
| Publication Date | January 12, 2020 |
| Submission Date | May 13, 2019 |
| Acceptance Date | September 12, 2019 |
| Published in Issue | Year 2020 Volume: 6 Issue: 1 |
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