Synthesis of Carbon-Nanomaterial from Rice Husk and Its Application as Adsorbent in Pesticide Residues Analysis

Oluwatosin Kayode Ogunbolude; Olatundun Funke Oyekanmi; Femi Timothy Olatunji; Christy Fumilayo Idowu; Abimbola Emily Aremu

doi:10.32571/ijct.1589832

Research Article

Year 2025, Volume: 9 Issue: 1, 56 - 68

Oluwatosin Kayode Ogunbolude , Olatundun Funke Oyekanmi , Femi Timothy Olatunji , Christy Fumilayo Idowu , Abimbola Emily Aremu

https://doi.org/10.32571/ijct.1589832

Abstract

Project Number

i589832

References

1. Ghoranneviss, M.; Soni, A.; Talebitaher, A.; Aslan. N. Journal of Nanomaterials, 2014, 2, 542-892.
2. Sabry, K.H.; Ariviyal. GR. 2021, 02, 05 – 021.
3. Pyrzynska, K.: Chemosphere, 2011, 83, 11, 1407- 1413.
4. Wepasnick, K.A.; Smith, B.A.; Bitter, J.L.; Fairbrother, D.H. Anal. Bioanal. Chem. 2010, 396, 1003–1014. 5. Fujishige, M.; Takeuchi, K.; Muramatsu, H.; Hayashi, T. Carbon Nanotube Hybrids.2015.
6. Zhou, J.J.; Sheng, Z.H.; Han, H.Y.; Zou, M.Q.; Li, C.Z. Materials Letter. 2012, 66, 222–224.
7. Puri, P. Int. J. Agric. Environ. Biotechnol. 2014, 7, 331-342.
8. Hafez, M.H.; Mohamed, G.G.; Omar, M.M. Egyptian Journal of Chemistry. 2024, 67(3), 181–193.
9. Olokoba, S.W.; Mciver, F.A. J. Mater. Environ. Sci. 2024 15, 9, 1208–1218.
10. Wang, Z.; Shoji, M.; Ogata, H. Appl Surf Sci 2011; 257: 9082-5.
11. Ismail, M.S.; Yusof, N.; Yusop. M.Z.; Ismail, A.F; Jaafar, F; Aziz, F.; Karim, Z.A. Malaysia Journal Fundamental Applied Science, 2009, (15), 516–521.
12. L.B. Abdulra’uf, L.B.; Lawal, A. Journal of Chemical Society of Nigeria, 2020, 45(6). 45-97.
13. Junaid, A.M.; Aliu, M.A.; Ibraheem, A.; Ishaq, A.; Lawal, A.; Sirhan, A.Y.; Tan, G.H.; Mustapha, A.O.;. Kazum, H.Y.; Abdulrauf, L.B. 2023 45, 5, 599–604.
14. Singh, P.; Bahadur, J.; Pal, K. Graphene. 2017, 6, 61–71.
15. Lou, Z.; Huang, H.; Li, M.; Shang, T.; Chen, C. Materials (Basel), 2014, 7:97–105.
16. Siddiqui. J. Environ. Chem. Eng. 2018, 7 (1) 1–11.
17. Rajan, R.; Zakaria, Y.; Shamsuddin, S.; Hassan, N.F. Malaysian Journal of Forensic Sciences. 2018, 8, 7–13.
18. Aliyev, E.; Filiz, V.; Khan, N.M.; Lee, Y.J.; Abetz, C.; Abetz, V. Nanomaterials. 2019, 8(9).
19. Lambert. Macmillan Publishing Company. 1987.
20. Lun, L.W.; An, A.G.; Kasim, F.H.; Arbain, D. AIP Conf Proc. 2017;1835:020049.
21. Packialakshmi, S.; Anuradha, B.; Nagamani, K.; Sarala, D.J.; Sujatha, S. Materials today Proceeding. 2021.
22. Wang, Z.; Shi, J.; Yin. ACS Appl. Mater. Interfaces. 2011, 3, 1127–1133.
23. Qazum, H. Y. published M.Sc Thesis submitted to the Kwara State University, Malete. 2021.

Synthesis of Carbon-Nanomaterial from Rice Husk and Its Application as Adsorbent in Pesticide Residues Analysis

Year 2025, Volume: 9 Issue: 1, 56 - 68

Oluwatosin Kayode Ogunbolude , Olatundun Funke Oyekanmi , Femi Timothy Olatunji , Christy Fumilayo Idowu , Abimbola Emily Aremu

https://doi.org/10.32571/ijct.1589832

Abstract

This study explores how rice husk, an abundant agricultural by-product, can be transformed into high-performance carbon nanomaterials with exceptional adsorption properties. The findings emphasize the potential of using sustainable and cost-effective resources to develop innovative materials for environmental and analytical applications. The synthesized carbon nano-structure was characterized using XRD, SEM, EDX, and FTIR. Notably, FTIR analysis revealed peaks at 1580.4 cm−1, 1597.79 cm−1, and 1456.38 cm−1, indicating C=C stretching and suggesting alkene or aromatic functional groups. EDX analysis showed varying weight percentages of carbon, oxygen, and sulfur for 30 g, 40 g, and 50 g samples. The rice husk-derived carbon nanomaterials were evaluated in the QuEChERS technique for extracting dichlorvos and bifenthrin from bean samples. The results showed that the sorbent properties were comparable to those of conventional PSA and C18, with high recovery rates for the investigated pesticides. This demonstrates efficient binding and removal of contaminants. The findings highlight the potential of using sustainable, cost-effective resources to develop innovative materials for environmental and analytical applications. Overall, this eco-friendly approach combines minimal environmental impact with high analytical performance, offering a promising alternative to traditional sorbents in sample preparation.

Keywords

Carbon-nanomaterial, rice husk waste, pesticides residues, QuEChERS, rice husk waste, XRD, SEM, EDX, FTIR

Project Number

i589832

References

1. Ghoranneviss, M.; Soni, A.; Talebitaher, A.; Aslan. N. Journal of Nanomaterials, 2014, 2, 542-892.
2. Sabry, K.H.; Ariviyal. GR. 2021, 02, 05 – 021.
3. Pyrzynska, K.: Chemosphere, 2011, 83, 11, 1407- 1413.
4. Wepasnick, K.A.; Smith, B.A.; Bitter, J.L.; Fairbrother, D.H. Anal. Bioanal. Chem. 2010, 396, 1003–1014. 5. Fujishige, M.; Takeuchi, K.; Muramatsu, H.; Hayashi, T. Carbon Nanotube Hybrids.2015.
6. Zhou, J.J.; Sheng, Z.H.; Han, H.Y.; Zou, M.Q.; Li, C.Z. Materials Letter. 2012, 66, 222–224.
7. Puri, P. Int. J. Agric. Environ. Biotechnol. 2014, 7, 331-342.
8. Hafez, M.H.; Mohamed, G.G.; Omar, M.M. Egyptian Journal of Chemistry. 2024, 67(3), 181–193.
9. Olokoba, S.W.; Mciver, F.A. J. Mater. Environ. Sci. 2024 15, 9, 1208–1218.
10. Wang, Z.; Shoji, M.; Ogata, H. Appl Surf Sci 2011; 257: 9082-5.
11. Ismail, M.S.; Yusof, N.; Yusop. M.Z.; Ismail, A.F; Jaafar, F; Aziz, F.; Karim, Z.A. Malaysia Journal Fundamental Applied Science, 2009, (15), 516–521.
12. L.B. Abdulra’uf, L.B.; Lawal, A. Journal of Chemical Society of Nigeria, 2020, 45(6). 45-97.
13. Junaid, A.M.; Aliu, M.A.; Ibraheem, A.; Ishaq, A.; Lawal, A.; Sirhan, A.Y.; Tan, G.H.; Mustapha, A.O.;. Kazum, H.Y.; Abdulrauf, L.B. 2023 45, 5, 599–604.
14. Singh, P.; Bahadur, J.; Pal, K. Graphene. 2017, 6, 61–71.
15. Lou, Z.; Huang, H.; Li, M.; Shang, T.; Chen, C. Materials (Basel), 2014, 7:97–105.
16. Siddiqui. J. Environ. Chem. Eng. 2018, 7 (1) 1–11.
17. Rajan, R.; Zakaria, Y.; Shamsuddin, S.; Hassan, N.F. Malaysian Journal of Forensic Sciences. 2018, 8, 7–13.
18. Aliyev, E.; Filiz, V.; Khan, N.M.; Lee, Y.J.; Abetz, C.; Abetz, V. Nanomaterials. 2019, 8(9).
19. Lambert. Macmillan Publishing Company. 1987.
20. Lun, L.W.; An, A.G.; Kasim, F.H.; Arbain, D. AIP Conf Proc. 2017;1835:020049.
21. Packialakshmi, S.; Anuradha, B.; Nagamani, K.; Sarala, D.J.; Sujatha, S. Materials today Proceeding. 2021.
22. Wang, Z.; Shi, J.; Yin. ACS Appl. Mater. Interfaces. 2011, 3, 1127–1133.
23. Qazum, H. Y. published M.Sc Thesis submitted to the Kwara State University, Malete. 2021.

There are 22 citations in total.

Details

Primary Language	English
Subjects	Classical Physics (Other)
Journal Section	Research Articles
Authors	Oluwatosin Kayode Ogunbolude 0009-0001-1341-1672 Olatundun Funke Oyekanmi 0009-0002-7817-9613 Femi Timothy Olatunji 0009-0006-1777-8128 Christy Fumilayo Idowu 0009-0001-4520-3528 Abimbola Emily Aremu 0009-0009-2089-8288
Project Number	i589832
Early Pub Date	June 2, 2025
Publication Date
Submission Date	November 23, 2024
Acceptance Date	June 2, 2025
Published in Issue	Year 2025 Volume: 9 Issue: 1

Cite

APA	Ogunbolude, O. K., Oyekanmi, O. F., Olatunji, F. T., Idowu, C. F., et al. (2025). Synthesis of Carbon-Nanomaterial from Rice Husk and Its Application as Adsorbent in Pesticide Residues Analysis. International Journal of Chemistry and Technology, 9(1), 56-68. https://doi.org/10.32571/ijct.1589832
AMA	Ogunbolude OK, Oyekanmi OF, Olatunji FT, Idowu CF, Aremu AE. Synthesis of Carbon-Nanomaterial from Rice Husk and Its Application as Adsorbent in Pesticide Residues Analysis. Int. J. Chem. Technol. June 2025;9(1):56-68. doi:10.32571/ijct.1589832
Chicago	Ogunbolude, Oluwatosin Kayode, Olatundun Funke Oyekanmi, Femi Timothy Olatunji, Christy Fumilayo Idowu, and Abimbola Emily Aremu. “Synthesis of Carbon-Nanomaterial from Rice Husk and Its Application As Adsorbent in Pesticide Residues Analysis”. International Journal of Chemistry and Technology 9, no. 1 (June 2025): 56-68. https://doi.org/10.32571/ijct.1589832.
EndNote	Ogunbolude OK, Oyekanmi OF, Olatunji FT, Idowu CF, Aremu AE (June 1, 2025) Synthesis of Carbon-Nanomaterial from Rice Husk and Its Application as Adsorbent in Pesticide Residues Analysis. International Journal of Chemistry and Technology 9 1 56–68.
IEEE	O. K. Ogunbolude, O. F. Oyekanmi, F. T. Olatunji, C. F. Idowu, and A. E. Aremu, “Synthesis of Carbon-Nanomaterial from Rice Husk and Its Application as Adsorbent in Pesticide Residues Analysis”, Int. J. Chem. Technol., vol. 9, no. 1, pp. 56–68, 2025, doi: 10.32571/ijct.1589832.
ISNAD	Ogunbolude, Oluwatosin Kayode et al. “Synthesis of Carbon-Nanomaterial from Rice Husk and Its Application As Adsorbent in Pesticide Residues Analysis”. International Journal of Chemistry and Technology 9/1 (June 2025), 56-68. https://doi.org/10.32571/ijct.1589832.
JAMA	Ogunbolude OK, Oyekanmi OF, Olatunji FT, Idowu CF, Aremu AE. Synthesis of Carbon-Nanomaterial from Rice Husk and Its Application as Adsorbent in Pesticide Residues Analysis. Int. J. Chem. Technol. 2025;9:56–68.
MLA	Ogunbolude, Oluwatosin Kayode et al. “Synthesis of Carbon-Nanomaterial from Rice Husk and Its Application As Adsorbent in Pesticide Residues Analysis”. International Journal of Chemistry and Technology, vol. 9, no. 1, 2025, pp. 56-68, doi:10.32571/ijct.1589832.
Vancouver	Ogunbolude OK, Oyekanmi OF, Olatunji FT, Idowu CF, Aremu AE. Synthesis of Carbon-Nanomaterial from Rice Husk and Its Application as Adsorbent in Pesticide Residues Analysis. Int. J. Chem. Technol. 2025;9(1):56-68.

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