EFFECT OF GRAPHITE AND MAX PHASE ON THE THERMAL AND DIELECTRIC PROPERTIES OF N-VINYL CARBAZOLE AND BENZYL METHACRYLATE COPOLYMER

Esra Barım; Emrah Gündoğdu

doi:10.36306/konjes.1585863

Research Article

Year 2025, Volume: 13 Issue: 2, 489 - 509, 01.06.2025

Esra Barım , Emrah Gündoğdu

https://doi.org/10.36306/konjes.1585863

Abstract

References

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EFFECT OF GRAPHITE AND MAX PHASE ON THE THERMAL AND DIELECTRIC PROPERTIES OF N-VINYL CARBAZOLE AND BENZYL METHACRYLATE COPOLYMER

Year 2025, Volume: 13 Issue: 2, 489 - 509, 01.06.2025

Esra Barım , Emrah Gündoğdu

https://doi.org/10.36306/konjes.1585863

Abstract

In this study, the P(N-vinyl carbazole-co-benzyl methacrylate) copolymer was synthesized, characterized by FT-IR/1H-NMR spectroscopic methods, and its composition was calculated from 1H NMR spectra. Composites of the copolymer with four different ratios of graphite (GR) and MAX phase (Ti3AlC2) by weight were prepared to obtain functional and novel electronic components for energy storage applications. Scanning electron microscopy, X-ray diffraction analyses were performed for some samples. Differential scanning calorimetry, thermogravimetric analysis curves were used to determine the thermal behavior of the materials. It was concluded that the composite with the highest glass transition temperatures and thermal stability was the composite with 10wt%GR/10wt%MAX additive. The thermal degradation kinetics of the copolymer and the composite containing 10wt%GR/10wt%MAX were investigated by applying the Flynn-Wall-Ozawa (FWO), Kissinger-Akahira-Sunose (KAS) methods and it was found that the thermal degradation activation energy of the composite was lower than that of the polymer. The dielectric properties of the materials were investigated at room temperature and between 0.1 kHz and 5 kHz. At 1 kHz the dielectric constants of the copolymer and 10wt%GR-doped composite were found to be 2.22 and 12.31, respectively. The composites doped with 10wt%GR and 10wt%GR/10wt%MAX were confirmed to be semiconductors.

Keywords

N-Vinylcarbazole, Benzyl Methacrylate, Graphite, MAX, Composite, Activation Energy, Dielectric

Ethical Statement

Authors declare to comply with all ethical guidelines including authorship, citation, data reporting, and publishing original research

References

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Primary Language	English
Subjects	Polymer Science and Technologies, Polymer Physics
Journal Section	Research Article
Authors	Esra Barım 0000-0003-0181-3102 Emrah Gündoğdu 0000-0001-9542-3601
Publication Date	June 1, 2025
Submission Date	November 15, 2024
Acceptance Date	April 9, 2025
Published in Issue	Year 2025 Volume: 13 Issue: 2

Cite

IEEE	E. Barım and E. Gündoğdu, “EFFECT OF GRAPHITE AND MAX PHASE ON THE THERMAL AND DIELECTRIC PROPERTIES OF N-VINYL CARBAZOLE AND BENZYL METHACRYLATE COPOLYMER”, KONJES, vol. 13, no. 2, pp. 489–509, 2025, doi: 10.36306/konjes.1585863.

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