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Year 2025, Volume: 10 Issue: 1, 69 - 88, 01.04.2025

Nardos Tesfalem Olango Ballekallu Chinna Eranna , Belete Yilma Hirpaye

https://doi.org/10.28978/nesciences.1631074

Abstract

References

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  • Jori, P. K., & Jadhav, V. H. (2022). Highly Efficient Zirconium Based Carbonaceous Solid Acid Catalyst for Selective Synthesis of 5-HMF from Fructose and Glucose in Isopropanol as a Solvent. Catalysis Letters, 152(6), 1703-1710. https://doi.org/10.1007/s10562-021-03764-9
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  • Ozyilmaz, A. T. (2023). Conducting Polymer Films on Zn Deposited Carbon Electrode. Natural and Engineering Sciences, 8(2), 129-139. https://doi.org/10.28978/nesciences.1342013
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Synthesis of Phosphonated Solid Acid Catalyst from Water Hyacinth-Derived Carbon Dots and Its Catalytic Performance in 5-Hydroxymethylfurfural Production

Year 2025, Volume: 10 Issue: 1, 69 - 88, 01.04.2025

Nardos Tesfalem Olango Ballekallu Chinna Eranna , Belete Yilma Hirpaye

https://doi.org/10.28978/nesciences.1631074

Abstract

The most effective parameters for the synthesis of Carbon Dots (CDs) obtained from Water Hyacinth (WH) were found to be 125 ̊C, 35 minutes, and 7 g, with a maximum yield of 18.65%, according to the Design Expert 13.0 program. The phosphonated solid acid catalyst (PCDs) was synthesized by functionalizing CDs with concentrated phosphoric acid (85%) at 150 ̊C for 6 hours and used as a catalyst for producing 5–hydroxymethylfurfural (5-HMF). UV, XRD, SEM, FTIR, TGA elemental analysis, and acid–base titration techniques were used to characterize the CDs and catalyst. The FTIR spectra confirm the synthesized catalyst exhibited functional groups such as -PO3H2, -COOH, and -OH. The Catalytic Performance of PCDs was evaluated in the one-step Microwave-Assisted (MW) conversion of WH into 5-HMF using a biphasic solvent (isopropanol: water), achieving a 73.05% yield at 90 ̊C in 40 minutes using 0.6 g of catalyst. For using crude biomass in 5-HMF production this method offers a green and efficient approach.

Keywords

Water hyacinth carbon dots solid acid catalyst 5-HMF

References

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  • Briscoe, J., Marinovic, A., Sevilla, M., Dunn, S., & Titirici, M. (2015). Biomass‐derived carbon quantum dot sensitizers for solid‐state nanostructured solar cells. Angewandte Chemie International Edition, 54(15), 4463-4468. https://doi.org/10.1002/anie.201409290
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  • da Luz Corrêa, A. P., Bastos, R. R. C., da Rocha Filho, G. N., Zamian, J. R., & da Conceição, L. R. V. (2020). Preparation of sulfonated carbon-based catalysts from murumuru kernel shell and their performance in the esterification reaction. RSC advances, 10(34), 20245-20256. https://doi.org/10.1039/D0RA03217D
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  • Gil Matellanes, M. V., Casal Banciella, M. D., Pevida García, C., Pis Martínez, J. J., & Rubiera González, F. (2010). Thermal behaviour and kinetics of coal/biomass blends during co-combustion. http://doi.org/10.1016/j.biortech.2010.02.008
  • He, Q., Lu, Y., Peng, Q., Chen, W., Fan, G., Chai, B., & Song, G. (2021). Synthesis of 5-hydroxymethylfurfural from fructose catalyzed by sulfonated carbon-based solid acid. Biomass Conversion and Biorefinery, 1-9. https://doi.org/10.1007/s13399-021-01847-6
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  • Issa, M. A., Abidin, Z. Z., Sobri, S., Abdul-Rashid, S., Mahdi, M. A., Ibrahim, N. A., & Pudza, M. Y. (2020). Fabrication, characterization and response surface method optimization for quantum efficiency of fluorescent nitrogen-doped carbon dots obtained from carboxymethylcellulose of oil palms empty fruit bunch. Chinese Journal of Chemical Engineering, 28(2), 584-592. https://doi.org/10.1016/j.cjche.2019.04.003
  • Jamil, F., Ala'a, H., Naushad, M., Baawain, M., Al-Mamun, A., Saxena, S. K., & Viswanadham, N. (2020). Evaluation of synthesized green carbon catalyst from waste date pits for tertiary butylation of phenol. Arabian journal of chemistry, 13(1), 298-307. https://doi.org/10.1016/j.arabjc.2017.04.009
  • Jori, P. K., & Jadhav, V. H. (2022). Highly Efficient Zirconium Based Carbonaceous Solid Acid Catalyst for Selective Synthesis of 5-HMF from Fructose and Glucose in Isopropanol as a Solvent. Catalysis Letters, 152(6), 1703-1710. https://doi.org/10.1007/s10562-021-03764-9
  • Khatiri, K., Sheikh, A., Hesam, R., & Alikhani, N. (2019). The Role of Participation in Preventing the Water Crisis. International Academic Journal of Innovative Research, 6(1), 47–52. https://doi.org/10.9756/IAJIR/V6I1/1910004
  • Li, M., Jiang, H., Zhang, L., Yu, X., Liu, H., Yagoub, A. E. A., & Zhou, C. (2020). Synthesis of 5-HMF from an ultrasound-ionic liquid pretreated sugarcane bagasse by using a microwave-solid acid/ionic liquid system. Industrial Crops and Products, 149, 112361. https://doi.org/10.1016/j.indcrop.2020.112361.
  • Ma, X., Dong, Y., Sun, H., & Chen, N. (2017). Highly fluorescent carbon dots from peanut shells as potential probes for copper ion: The optimization and analysis of the synthetic process. Materials Today Chemistry, 5, 1-10. https://doi.org/10.1016/j.mtchem.2017.04.004
  • Majdanishabestari, K., & Soleimani, M. (2019). Using simulation-optimization model in water resource management with consideration of environmental issues. International Academic Journal of Science and Engineering, 6(1), 15–25. https://doi.org/10.9756/IAJSE/V6I1/1910002
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  • Nandini, G. K. (2024). IOT Use in a farming area to manage water conveyance. Archives for Technical Sciences/Arhiv za Tehnicke Nauke, (31). https://doi.org/10.70102/afts.2024.1631.016.
  • Of, P., Acid, S., From, C., Husk, R., Of, I., Catalytic, I. T. S., & In, P. (2017). Preparation of Solid Acid Catalyst from Rice Husk and by Abel Aklilu A Thesis Submitted to The School of Chemical and Bio-Engineering Presented in Fulfilment of the Requirement for the Degree of Master of Science (Process Engineering) Addis Ababa Univer. October.
  • Ozyilmaz, A. T. (2023). Conducting Polymer Films on Zn Deposited Carbon Electrode. Natural and Engineering Sciences, 8(2), 129-139. https://doi.org/10.28978/nesciences.1342013
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  • Peng, D., Qiao, S., Luo, Y., Ma, H., Zhang, L., Hou, S., ... & Xu, H. (2020). Performance of microbial induced carbonate precipitation for immobilizing Cd in water and soil. Journal of hazardous materials, 400, 123116. https://doi.org/10.1016/j.jhazmat.2020.123116
  • Prathumsuwan, T., Jaiyong, P., In, I., & Paoprasert, P. (2019). Label-free carbon dots from water hyacinth leaves as a highly fluorescent probe for selective and sensitive detection of borax. Sensors and Actuators B: Chemical, 299, 126936. https://doi.org/10.1016/j.snb.2019.126936
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There are 48 citations in total.

Details

Primary Language English
Subjects Structural Biology
Journal Section Articles
Authors

Nardos Tesfalem Olango 0009-0005-3519-9069

Ballekallu Chinna Eranna

Belete Yilma Hirpaye 0000-0002-7084-997X

Publication Date April 1, 2025
Submission Date February 1, 2025
Acceptance Date April 1, 2025
Published in Issue Year 2025 Volume: 10 Issue: 1

Cite

APA Olango, N. T., Eranna, B. C., & Hirpaye, B. Y. (2025). Synthesis of Phosphonated Solid Acid Catalyst from Water Hyacinth-Derived Carbon Dots and Its Catalytic Performance in 5-Hydroxymethylfurfural Production. Natural and Engineering Sciences, 10(1), 69-88. https://doi.org/10.28978/nesciences.1631074

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