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Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature

Year 2016, Volume: 2 Issue: 3, 56 - 61, 15.11.2016

Hasan Erge Hakan Turan Ali Riza Kul

https://doi.org/10.20863/nsd.277898

Abstract





Objective: In this study, the solubility, density,
conductivity and phase equilibria of the Na2(H2PO2)2-Ba(H2PO2)2-H2O
ternary system located in the structure of the Na+, Ba2+, (H2PO2)-//H2O
quaternary reciprocal
water-salt system were investigated using physicochemical analysis methods.


Material and
Methods: Riedel-de Haen and Merck salts were used
to investigate the solubility and phase equilibria of the Na2(H2PO2)2
-Ba(H2PO2)2-H2O ternary water–salt system at room temperature


Results: It was determined that the Na2(H2PO2)2-Ba(H2PO2)2-H2O
ternary water-salt system belongs to the simple eutonic system type and the
compositions corresponding to the eutonic point, expressed as mass %, were
50.73, 0.53 and 48.74 (w/w %) for Na2(H2PO2)2,
Ba(H2PO2)2 and H2O, respectively

Keywords

Na2(H2PO2)2-Ba(H2PO2)2-H2O Ternary Water-Salt System Isothermic System Density Solubility

References

  • 1. Özdek U. 2009. NaCl-Ba(H2PO2)2-H2O Üçlü Su-Tuz Sisteminin Oda Sıcaklığında İzotermik Yöntemle Çözünürlüğünün ve Faz Dengelerinin Araştırılması (unpublished master’s thesis). YYÜ, Fen Bilimleri Enstitüsü, Van.
  • 2. Alişoğlu V. 1973. Potasyum ve Manganın Bromür ve Sülfatlarını İhtiva Eden Karşılıklı Su-Tuz Sisteminin Fizikokimyasal Araştırılması (doctoral thesis). Bakü.
  • 3. Erge H, Adıgüzel V, Alişoğlu V. Study of the solubility İn Na–Ba–Cl–H2O, Na–Ba–H2PO2–H2O, Na–Cl–H2PO2–H2O, and Ba–Cl–H2PO2–H2O ternaries, and İn Na+, Ba2+/Cl−, (H2PO2)−//H2O reciprocal quaternary system at 0 ◦C. Elsevier. 2013; 344:13–18.
  • 4. Aliev VA, Velieva SM, 1985. Sodium chloride manganese-hypophosphate-water system at 20-degrees-c. Zr. Neorg. Khim. 1985; 30:798-800.
  • 5. Adıgüzel V, Erge H, Alişoğlu V, Necefoğlu H. Study of the solubility, viscosity and density in Na+ , Zn2+/Cl H2O, Na+ Zn2+ (H2PO2) H2O, Na+ , Cl/(H2PO2) H2O, and Zn2+, Cl/(H2PO2) H2O ternary systems, and in Na+ , Zn2+/Cl, (H2PO2) //H2O reciprocal quaternary system at 273.15 K. Elsevier. 2014; 75:35–44.
  • 6. Erge H, Adıgüzel V, Kul AR, Karatay O, Yenigün A. BaCl2- Ba(H2PO2)2- H2O üçlü sisteminin 00C ve +250C'de çözünürlüğünün ve faz dengelerinin araştırılması. 25. Ulusal Kimya Kongresi, 27 Haziran-2 Temmuz 2011, Erzurum, Türkiye.
  • 7. Gülensoy H. Kompleksometrinin esasları ve kompleksometrik titrasyonlar kitabı, Türkiye Kimya Derneği Yayınları. 2003; 255: 126-131.
  • 8. Erge H, Adıgüzel V, Kul AR, Alişoğlu V. Na2Cl2/BaCl2/ Ba(H2PO2)2/ H2O sisteminin fizikokimyasal analizi. Kafkas Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2008; 1: 33-36.

Year 2016, Volume: 2 Issue: 3, 56 - 61, 15.11.2016

Hasan Erge Hakan Turan Ali Riza Kul

https://doi.org/10.20863/nsd.277898

Abstract

References

  • 1. Özdek U. 2009. NaCl-Ba(H2PO2)2-H2O Üçlü Su-Tuz Sisteminin Oda Sıcaklığında İzotermik Yöntemle Çözünürlüğünün ve Faz Dengelerinin Araştırılması (unpublished master’s thesis). YYÜ, Fen Bilimleri Enstitüsü, Van.
  • 2. Alişoğlu V. 1973. Potasyum ve Manganın Bromür ve Sülfatlarını İhtiva Eden Karşılıklı Su-Tuz Sisteminin Fizikokimyasal Araştırılması (doctoral thesis). Bakü.
  • 3. Erge H, Adıgüzel V, Alişoğlu V. Study of the solubility İn Na–Ba–Cl–H2O, Na–Ba–H2PO2–H2O, Na–Cl–H2PO2–H2O, and Ba–Cl–H2PO2–H2O ternaries, and İn Na+, Ba2+/Cl−, (H2PO2)−//H2O reciprocal quaternary system at 0 ◦C. Elsevier. 2013; 344:13–18.
  • 4. Aliev VA, Velieva SM, 1985. Sodium chloride manganese-hypophosphate-water system at 20-degrees-c. Zr. Neorg. Khim. 1985; 30:798-800.
  • 5. Adıgüzel V, Erge H, Alişoğlu V, Necefoğlu H. Study of the solubility, viscosity and density in Na+ , Zn2+/Cl H2O, Na+ Zn2+ (H2PO2) H2O, Na+ , Cl/(H2PO2) H2O, and Zn2+, Cl/(H2PO2) H2O ternary systems, and in Na+ , Zn2+/Cl, (H2PO2) //H2O reciprocal quaternary system at 273.15 K. Elsevier. 2014; 75:35–44.
  • 6. Erge H, Adıgüzel V, Kul AR, Karatay O, Yenigün A. BaCl2- Ba(H2PO2)2- H2O üçlü sisteminin 00C ve +250C'de çözünürlüğünün ve faz dengelerinin araştırılması. 25. Ulusal Kimya Kongresi, 27 Haziran-2 Temmuz 2011, Erzurum, Türkiye.
  • 7. Gülensoy H. Kompleksometrinin esasları ve kompleksometrik titrasyonlar kitabı, Türkiye Kimya Derneği Yayınları. 2003; 255: 126-131.
  • 8. Erge H, Adıgüzel V, Kul AR, Alişoğlu V. Na2Cl2/BaCl2/ Ba(H2PO2)2/ H2O sisteminin fizikokimyasal analizi. Kafkas Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2008; 1: 33-36.
There are 8 citations in total.

Details

Journal Section Original Articles
Authors

Hasan Erge

Hakan Turan

Ali Riza Kul

Publication Date November 15, 2016
Published in Issue Year 2016 Volume: 2 Issue: 3

Cite

APA Erge, H., Turan, H., & Kul, A. R. (2016). Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature. Natural Science and Discovery, 2(3), 56-61. https://doi.org/10.20863/nsd.277898
AMA Erge H, Turan H, Kul AR. Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature. Nat Sci Discov. September 2016;2(3):56-61. doi:10.20863/nsd.277898
Chicago Erge, Hasan, Hakan Turan, and Ali Riza Kul. “Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature”. Natural Science and Discovery 2, no. 3 (September 2016): 56-61. https://doi.org/10.20863/nsd.277898.
EndNote Erge H, Turan H, Kul AR (September 1, 2016) Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature. Natural Science and Discovery 2 3 56–61.
IEEE H. Erge, H. Turan, and A. R. Kul, “Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature”, Nat Sci Discov, vol. 2, no. 3, pp. 56–61, 2016, doi: 10.20863/nsd.277898.
ISNAD Erge, Hasan et al. “Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature”. Natural Science and Discovery 2/3 (September 2016), 56-61. https://doi.org/10.20863/nsd.277898.
JAMA Erge H, Turan H, Kul AR. Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature. Nat Sci Discov. 2016;2:56–61.
MLA Erge, Hasan et al. “Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature”. Natural Science and Discovery, vol. 2, no. 3, 2016, pp. 56-61, doi:10.20863/nsd.277898.
Vancouver Erge H, Turan H, Kul AR. Investigation of the Na2(H2PO2)2 - Ba(H2PO2)2 - H2O Water-Salt Ternary System at Room Temperature. Nat Sci Discov. 2016;2(3):56-61.
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