Öz
Anahtar Kelimeler
Kaynakça
- [1] Wilkins, P.C., Wilkins, R.G., Inorganic Chemistry in Biology , Oxford University Press, Oxford, 9-10 (1997)
- [2] Kokko, K.P., Hooper, H.B., ve Dix, T.A., Synthesis of cyclic and acyclic N -methyl-N - alkyl-L-arginine analogues Tetrahedron Letters, 45: 2151-2153, (2004)
- [3] Li, X., Atkinson, R.N. ve King, S.B., Preparation and evaluation of new L-canavanine derivatives as nitric oxide synthase inhibitors Tetrahedron, 57: 6557-6565, (2001).
- [4] ak yan, ., Gündüz, N., Gündüz, T.,"Synt- hesis and characterization of manganese(III) complexes of schiff bases derived from amino acids and 2-hydroxy-1-naphthaldehyde , Synth. React. Inorg. Met.-Org. Chem. 31 (7): 1175 1187 (2001).
- [5] ak yan, . ve Y lmaz, H., Manganese(III) complexes of some amino Acid (L-serine, L- methionine, L-cystein) Schiff bases derived from 2- hydroxy -1-naphthaldehyde Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry , 33 (6): 971-983 (2003).
- [6] Özcan, Y., de, S., ak yan, ., Lo o lu, E., Structure and Characterization of N-(2-Hydroxy-1- naphthylidene) threonine J. Mol. Struct. 658, 207- 213 (2003).
- [7] Özcan, Y., ak yan, , de, S., Crystal structure of a histidine Schiff base IUCR, XX Congress of International Union of Crystallography, Acta Crys., A61, C289 (2005).
- [8] Kaitner B., Pavlovic G., A Reinvestigation of the Quinoidal Effect in N-n-Propyl-2-oxo-1- naphthylidenemethylamine Acta Cryst. C52, 2573- 2575 (1996).
- [9] Higelin, D., Sixl, H., Spectroscopic stu-dies of the photochromism of N-salicyli-deneaniline mixed crystals and glasses 1983, Chem Phys. 77, 391- 400.
- [10] Cohen, M.D., Schmidt, G.M.J., Flavian S., Topochemistry Part VI. Experiments on photochromy and hermochromy of crystalline anils of salicylaldehydes 1964, J. Chem. Soc. 2041- 2051.
- [11] Liu, G-F, Liu, L., Jia, D-Z, Yu, K-B, Synthesis and crystal structure of 2-anilino-6H-5- (1-phenyl-3-methyl-5-pyrazolone-4-ylene)-1,3,4- thiadiazine 2004, J.Chem. Cryst. Vol.34 No 12.,835-841.
- [12] Orpen A.G., Brammer L., Allen F.H., Kennard O., Watson D.G., Taylor R., "Tables of bond bengths determined by X-Ray and neutron diffraction. Part 2. Organometallic compounds and coordination complexes of the d- and f-Block Metals," 1989, J.Chem.-Soc.Dalton Trans.Suppl. S1-S 83.
- [13]Elerman, Y., Kabak, M., Elmal , A., Suobada,I., 1-[N-(4-Methyl-2-pyridyl) amino- methylidene]-2(1H)-naphthalenone Acta Cryst. C54, 128-130, (1998)
- [14] Sheldrick, G.M. SHELXS97 and SHELXL97 University of Göttingen, Germany, 1997.
Öz
[N-(2-hidroksi-1-naftaliden)histidin] Schiff baz sentezlenerek yap s , IR, UV, 1H NMR spektroskopi metodlar ve Xortorombik ve P212121 uzay grubuna sahiptir. Kristalografik parametreleri ise a=6.133(5), b=7.168(5), c=33.639(5)Å , V=1478.8(2) Å3 birim hücre bilgilerini içerir. Ayd nlat lan yap n n do rulu unun bir ölçüsü olan R faktörleri ise R=0.0394 , wR=0.0784 olarak belirlenmi tir. Bu tip Schiff bazlar sahip olduklar tautomerik formlara ba l olarak fotokromik veya termokromik karakter gösterirler. Daha önceki çal mam zda inceledi imiz treonin Schiff baz nda gözlenen enol-imin tautomerli inin aksine histidin Schiff baz n n kat fazda daha çok keto-amin tautomerli ini tercih etti i görülmü tür. Molekül içi hidrojen ba [ N-Hketo-amin formundaki yük da l m na ba l olarak kuvvetli naftaliden grubundan azot atomuna proton transferinin oldu unu göstermektedir
Anahtar Kelimeler
Histidin Schiff baz Hidroksinaftaldehit X-I nlar kristalografi
Kaynakça
- [1] Wilkins, P.C., Wilkins, R.G., Inorganic Chemistry in Biology , Oxford University Press, Oxford, 9-10 (1997)
- [2] Kokko, K.P., Hooper, H.B., ve Dix, T.A., Synthesis of cyclic and acyclic N -methyl-N - alkyl-L-arginine analogues Tetrahedron Letters, 45: 2151-2153, (2004)
- [3] Li, X., Atkinson, R.N. ve King, S.B., Preparation and evaluation of new L-canavanine derivatives as nitric oxide synthase inhibitors Tetrahedron, 57: 6557-6565, (2001).
- [4] ak yan, ., Gündüz, N., Gündüz, T.,"Synt- hesis and characterization of manganese(III) complexes of schiff bases derived from amino acids and 2-hydroxy-1-naphthaldehyde , Synth. React. Inorg. Met.-Org. Chem. 31 (7): 1175 1187 (2001).
- [5] ak yan, . ve Y lmaz, H., Manganese(III) complexes of some amino Acid (L-serine, L- methionine, L-cystein) Schiff bases derived from 2- hydroxy -1-naphthaldehyde Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry , 33 (6): 971-983 (2003).
- [6] Özcan, Y., de, S., ak yan, ., Lo o lu, E., Structure and Characterization of N-(2-Hydroxy-1- naphthylidene) threonine J. Mol. Struct. 658, 207- 213 (2003).
- [7] Özcan, Y., ak yan, , de, S., Crystal structure of a histidine Schiff base IUCR, XX Congress of International Union of Crystallography, Acta Crys., A61, C289 (2005).
- [8] Kaitner B., Pavlovic G., A Reinvestigation of the Quinoidal Effect in N-n-Propyl-2-oxo-1- naphthylidenemethylamine Acta Cryst. C52, 2573- 2575 (1996).
- [9] Higelin, D., Sixl, H., Spectroscopic stu-dies of the photochromism of N-salicyli-deneaniline mixed crystals and glasses 1983, Chem Phys. 77, 391- 400.
- [10] Cohen, M.D., Schmidt, G.M.J., Flavian S., Topochemistry Part VI. Experiments on photochromy and hermochromy of crystalline anils of salicylaldehydes 1964, J. Chem. Soc. 2041- 2051.
- [11] Liu, G-F, Liu, L., Jia, D-Z, Yu, K-B, Synthesis and crystal structure of 2-anilino-6H-5- (1-phenyl-3-methyl-5-pyrazolone-4-ylene)-1,3,4- thiadiazine 2004, J.Chem. Cryst. Vol.34 No 12.,835-841.
- [12] Orpen A.G., Brammer L., Allen F.H., Kennard O., Watson D.G., Taylor R., "Tables of bond bengths determined by X-Ray and neutron diffraction. Part 2. Organometallic compounds and coordination complexes of the d- and f-Block Metals," 1989, J.Chem.-Soc.Dalton Trans.Suppl. S1-S 83.
- [13]Elerman, Y., Kabak, M., Elmal , A., Suobada,I., 1-[N-(4-Methyl-2-pyridyl) amino- methylidene]-2(1H)-naphthalenone Acta Cryst. C54, 128-130, (1998)
- [14] Sheldrick, G.M. SHELXS97 and SHELXL97 University of Göttingen, Germany, 1997.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Bölüm | Makaleler |
| Yazarlar | |
| Yayımlanma Tarihi | 1 Haziran 2006 |
| Yayımlandığı Sayı | Yıl 2006 Cilt: 2 Sayı: 2 |