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Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method

Yıl 2009, Cilt: 22 Sayı: 3, 157 - 167, 26.03.2010

Poonam Kaur Usha Gupta

Öz

H-point standard addition method (HPSAM) was applied to kinetic data for simultaneous determination of Ni(II) and Mn(II). The method is based on the difference between rate of complexation of 1-(2-pyridylazo)-2- naphthol (PAN) with Ni(II) and Mn(II) at pH 7.5 in Triton X-100 micellar media. Ni(II) and Mn(II) can be determined simultaneously in the concentration range 0.084-0.734 and 0.055-0.366 8g mL-1, respectively. The proposed method has successfully been applied for simultaneous determination of Ni(II) and Mn(II) in synthetic samples, spiked water samples, alloys and food products.

 

Key Words: Nickel; Manganese; Kinetic; HPSAM; PAN.

Anahtar Kelimeler

-

Kaynakça

  • Bosch-Reig, F., Campins-Falco, P., “H-point Standard Additions Method Application to Analytical Spectroscopy”, Analyst, 113: 1011-1016 (1988). Fundamentals and extensively method”, Fresenius J. Anal. Chem., 338: 16-21 (1990). or completely [4] Afkhami, A., Zarei, A.R., “Simultaneous Spectrophotometric Determination of Bi(III) and Sb(III) Based on Their Complexes with Iodide in Acidic Media Using the H-Point Standard Addition Method and First Derivative Spectrophotometry”,
  • Anal. Sci., 19: 917-921 (2003).
  • Bosch-Reig, F., Campins-Falco, P., Verdu-Andres, J., “Evaluation and elimination of the “blank bias errror” using the H-point standard addition method: application to spectrophotometric determination on using absorbent blank”, Anal. Chim. Acta, 270 (1): 253-265 (1992).
  • Bosch-Reig, F., Campins-Falco, P., Verdu-Andres, J., Molins-Legua, C., “Study of the behaviour of the absorbent blanks in analytical procedures by using the H-Point standard additions method (HPSAM)”, Talanta, 41 (1): 39-52 (1994).
  • Blasco-Gomez, F., Bosch-Reig, F., Campins-Falco, P., Molins-Legua, C., “H-point curve isolation method for coupled liquid chromatography and UV-Visible spectrophotometry”, Anal. Chem., 72: 2559-2565 (2000).
  • Zolgharnein, J., Abdollahi, H., Jafarifar, D., Azimi G.H., “Simultaneous determination of Fe (II) and Fe (III) by kinetic spectrophotometric H-point standard addition method”, Talanta, 57: 1067-1073 (2002).
  • Bosch-Reig, F., Campins-Falco, P., Sevillano-Cabez, A., “Development of the H-Point Standard-Additions Method for Ultraviolet-Visible Spectroscopic Kinetic Analysis of Two-Component Systems”, Anal. Chem., 63: 2424-2429 (1991). R., Molins-Legua, C., [10] Safavi, A., Abdollahi, H., Nezhad, M.R.H., “Simultaneous kinetic determination of Fe(III) and Fe(II) by H-point standard addition method”, Talanta, 56: 699-704 (2002).
  • Safavi, A., Abdollahi, H., Sedaghatpour, F., Zeinalli, S., “Kinetic spectrophotometric determination of V(IV) in the presence of V(V) by the H-point standard addition method”, Anal. Chim. Acta, 409: 275-282 (2000).
  • Nielsen, F.H., Nutrition in Health and Disease 9th ed., Baltimore: Williams & Wilkins, 283-303 (1999).
  • Andrews, R. K., Blakeley, R.L., Zerner, B., Lancaster, J.R., The Bioinorganic Chemistry of Nickel, VCH, New York, 141-165 (1988).
  • Teo, K.C., Chen, J., “Determination of manganese in water spectrometry after cloud point extraction”, Analyst, 126: 534-537 (2001). atomic absorption
  • Sirko, A., Brodzik, R., “Plant ureases: Roles and regulation”, Acta Biochim. Pol., 47 (4): 1189-1195 (2000).
  • Adriana, P.D.O., Mercedes, D. M., Anchieta, G.N.J., Claudio, L.E., “Simultaneous determination of Al, As, Cu, Fe, Mn, and Ni in fuel ethanol by GFAAS”, At. Spectrosc., 23(2): 39-43 (2002).
  • Ghoneim, M.M., Hassanein, A.M., Hammam, E., Beltagi, A.M., “Simultaneous determination of Cd, Pb, Cu, Sb, Bi, Se, Zn, Mn, Ni, Co and Fe in water samples by differential pulse stripping voltammetry at a hanging mercury drop electrode”, Fresenius, J. Anal. Chem., 367 (4): 378-383 (2000).
  • Fredrikson, M., Carlsson, N.G., Almgren, A., Sandberg, A.S., “Simultaneous and Sensitive Analysis of Cu, Ni, Zn, Co, Mn, and Fe in Food and Biological Samples by Ion Chromatography”, J. Agric. Food. Chem., 50: 59-65 (2002).
  • Mclntire, G.L., Dorsey, J.G., “Micelles in Analytical Chemistry”, Cri. Rev. Anal. Chem., 21(4): 257-278 (1990).
  • Singh, H.B., Agnihotri, N.K., Singh, V.K., “ Non- extractive determination of cobalt in micellar medium”, Talanta, 48: 623-631 (1999). Spectrophotometric
  • Second Annual Report on Carcinogens, Environmental Protection Agency, NTP, 81-43:73-75, 78-80(1981).

Yıl 2009, Cilt: 22 Sayı: 3, 157 - 167, 26.03.2010

Poonam Kaur Usha Gupta

Öz

Kaynakça

  • Bosch-Reig, F., Campins-Falco, P., “H-point Standard Additions Method Application to Analytical Spectroscopy”, Analyst, 113: 1011-1016 (1988). Fundamentals and extensively method”, Fresenius J. Anal. Chem., 338: 16-21 (1990). or completely [4] Afkhami, A., Zarei, A.R., “Simultaneous Spectrophotometric Determination of Bi(III) and Sb(III) Based on Their Complexes with Iodide in Acidic Media Using the H-Point Standard Addition Method and First Derivative Spectrophotometry”,
  • Anal. Sci., 19: 917-921 (2003).
  • Bosch-Reig, F., Campins-Falco, P., Verdu-Andres, J., “Evaluation and elimination of the “blank bias errror” using the H-point standard addition method: application to spectrophotometric determination on using absorbent blank”, Anal. Chim. Acta, 270 (1): 253-265 (1992).
  • Bosch-Reig, F., Campins-Falco, P., Verdu-Andres, J., Molins-Legua, C., “Study of the behaviour of the absorbent blanks in analytical procedures by using the H-Point standard additions method (HPSAM)”, Talanta, 41 (1): 39-52 (1994).
  • Blasco-Gomez, F., Bosch-Reig, F., Campins-Falco, P., Molins-Legua, C., “H-point curve isolation method for coupled liquid chromatography and UV-Visible spectrophotometry”, Anal. Chem., 72: 2559-2565 (2000).
  • Zolgharnein, J., Abdollahi, H., Jafarifar, D., Azimi G.H., “Simultaneous determination of Fe (II) and Fe (III) by kinetic spectrophotometric H-point standard addition method”, Talanta, 57: 1067-1073 (2002).
  • Bosch-Reig, F., Campins-Falco, P., Sevillano-Cabez, A., “Development of the H-Point Standard-Additions Method for Ultraviolet-Visible Spectroscopic Kinetic Analysis of Two-Component Systems”, Anal. Chem., 63: 2424-2429 (1991). R., Molins-Legua, C., [10] Safavi, A., Abdollahi, H., Nezhad, M.R.H., “Simultaneous kinetic determination of Fe(III) and Fe(II) by H-point standard addition method”, Talanta, 56: 699-704 (2002).
  • Safavi, A., Abdollahi, H., Sedaghatpour, F., Zeinalli, S., “Kinetic spectrophotometric determination of V(IV) in the presence of V(V) by the H-point standard addition method”, Anal. Chim. Acta, 409: 275-282 (2000).
  • Nielsen, F.H., Nutrition in Health and Disease 9th ed., Baltimore: Williams & Wilkins, 283-303 (1999).
  • Andrews, R. K., Blakeley, R.L., Zerner, B., Lancaster, J.R., The Bioinorganic Chemistry of Nickel, VCH, New York, 141-165 (1988).
  • Teo, K.C., Chen, J., “Determination of manganese in water spectrometry after cloud point extraction”, Analyst, 126: 534-537 (2001). atomic absorption
  • Sirko, A., Brodzik, R., “Plant ureases: Roles and regulation”, Acta Biochim. Pol., 47 (4): 1189-1195 (2000).
  • Adriana, P.D.O., Mercedes, D. M., Anchieta, G.N.J., Claudio, L.E., “Simultaneous determination of Al, As, Cu, Fe, Mn, and Ni in fuel ethanol by GFAAS”, At. Spectrosc., 23(2): 39-43 (2002).
  • Ghoneim, M.M., Hassanein, A.M., Hammam, E., Beltagi, A.M., “Simultaneous determination of Cd, Pb, Cu, Sb, Bi, Se, Zn, Mn, Ni, Co and Fe in water samples by differential pulse stripping voltammetry at a hanging mercury drop electrode”, Fresenius, J. Anal. Chem., 367 (4): 378-383 (2000).
  • Fredrikson, M., Carlsson, N.G., Almgren, A., Sandberg, A.S., “Simultaneous and Sensitive Analysis of Cu, Ni, Zn, Co, Mn, and Fe in Food and Biological Samples by Ion Chromatography”, J. Agric. Food. Chem., 50: 59-65 (2002).
  • Mclntire, G.L., Dorsey, J.G., “Micelles in Analytical Chemistry”, Cri. Rev. Anal. Chem., 21(4): 257-278 (1990).
  • Singh, H.B., Agnihotri, N.K., Singh, V.K., “ Non- extractive determination of cobalt in micellar medium”, Talanta, 48: 623-631 (1999). Spectrophotometric
  • Second Annual Report on Carcinogens, Environmental Protection Agency, NTP, 81-43:73-75, 78-80(1981).
Toplam 18 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Chemistry
Yazarlar

Poonam Kaur

Usha Gupta

Yayımlanma Tarihi 26 Mart 2010
Yayımlandığı Sayı Yıl 2009 Cilt: 22 Sayı: 3

Kaynak Göster

APA Kaur, P., & Gupta, U. (2010). Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method. Gazi University Journal of Science, 22(3), 157-167.
AMA Kaur P, Gupta U. Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method. Gazi University Journal of Science. Mart 2010;22(3):157-167.
Chicago Kaur, Poonam, ve Usha Gupta. “Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method”. Gazi University Journal of Science 22, sy. 3 (Mart 2010): 157-67.
EndNote Kaur P, Gupta U (01 Mart 2010) Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method. Gazi University Journal of Science 22 3 157–167.
IEEE P. Kaur ve U. Gupta, “Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method”, Gazi University Journal of Science, c. 22, sy. 3, ss. 157–167, 2010.
ISNAD Kaur, Poonam - Gupta, Usha. “Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method”. Gazi University Journal of Science 22/3 (Mart 2010), 157-167.
JAMA Kaur P, Gupta U. Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method. Gazi University Journal of Science. 2010;22:157–167.
MLA Kaur, Poonam ve Usha Gupta. “Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method”. Gazi University Journal of Science, c. 22, sy. 3, 2010, ss. 157-6.
Vancouver Kaur P, Gupta U. Determination of Nickel and Manganese by Kinetic H-Point Standard Addition Method. Gazi University Journal of Science. 2010;22(3):157-6.