Gold Nanoparticle and Poly Arginine Modified GCE for Simultaneous Determination of Hydroquinone and Catechol

Gözde Aydoğdu Tığ

Gold Nanoparticle and Poly Arginine Modified GCE for Simultaneous Determination of Hydroquinone and Catechol

Yıl 2017, Cilt: 45 Sayı: 3, 443 - 451, 01.09.2017

Gözde Aydoğdu Tığ

Öz

In this work, a novel electrochemical sensor based on gold nanoparticle AuNP and poly L-arginine P AG modified glassy carbon electrode GCE P AG /AuNP/GCE was designed to determine hydroquinone HQ and catechol CC . Scanning electron microscopy SEM , cyclic voltammetry CV and electrochemical impedance spectroscopy EIS were utilized to characterize the P AG /AuNP/GCE. Differential pulse voltammetry DPV results revealed that the modified GCE represented high selectivity for the simultaneous determination of HQ and CC. The linear working ranges of HQ and CC were in the concentration range of 5.0 to 600.0 μmol L-1 with the detection limits of 1.5 and 1.42 μmol L-1, respectively. The prepared sensor is a suitable tool with low cost for the rapid analysis of HQ and CC in the real samples with high recoveries.

Anahtar Kelimeler

Hydroquinone, catechol, simultaneous, poly arginine, AuNP

Kaynakça

Y. Wang, J. Qu, S. Li, Y. Dong, J. Qu, Simultaneous determination of hydroquinone and catechol using a glassy carbon electrode modified with gold nanoparticles, ZnS/NiS@ZnS quantum dots and L-cysteine, Microchim. Acta, 182 (2015) 2277-2283.
P. Nagaraja, R.A. Vasantha, K.R. Sunitha, A sensitive and selective spectrophotometric estimation of catechol derivatives in pharmaceutical preparations, Talanta, 55 (2001) 1039-1046.
G. Marrubini, E. Calleri, T. Coccini, A.F. Castoldi, L. Manzo, Direct Analysis of Phenol, Catechol and Hydroquinone in Human Urine by Coupled-Column HPLC with Fluorimetric Detection, Chromatographia, (2005) 25-31.
M.F. Pistonesi, M.S. Di Nezio, M.E. Centurión, M.E. Palomeque, A.G. Lista, B.S. Fernández Band, Determination of phenol, resorcinol and hydroquinone in air samples by synchronous fluorescence using partial least-squares (PLS), Talanta, 69 (2006) 1265
B. Unnikrishnan, P.-L. Ru, S.-M. Chen, Electrochemically synthesized Pt–MnO2 composite particles for simultaneous determination of catechol and hydroquinone, Sens. Actuat. B: Chem., 169 (2012) 242.
Z. Guo, Y. Lu, J. Li, X.-f. Xu, G.-q. Huang, Z.-y. Wang, catechol using an electrode modified by a composite of graphene/lanthanum hydroxide nanowires, Anal. Methods, 6 (2014) 8314-8320.
W. Si, W. Lei, Y. Zhang, M. Xia, F. Wang, Q. Hao, Electrodeposition of graphene oxide doped poly(3,4- ethylenedioxythiophene) film and its electrochemical sensing of catechol and hydroquinone, Electrochim. Acta, 85 (2012) 295-301.
D.P. Santos, M.F. Bergamini, A.G. Fogg, M.V.B. Zanoni, Application of a Glassy Carbon Electrode Modified with Poly(Glutamic Acid) in Caffeic Acid Determination, Microchim. Acta, 151 (2005) 127-134.
K. Zhang, P. Luo, J. Wu, W. Wang, B. Ye, Highly sensitive determination of Sunset Yellow in drink using a poly (l-cysteine) modified glassy carbon electrode, Anal. Methods, 5 (2013) 5044-5050.
Z. Guo, G.-q. Huang, J. Li, Z.-y. Wang, X.-f. Xu, Graphene oxide-Ag/poly-l-lysine modified glassy carbon electrode as an electrochemical sensor for the determination of dopamine in the presence of ascorbic acid, J. Electroanal. Chem., 759, Part 2 (2015) 113-121.
Y. Yi, G. Zhu, X. Wu, K. Wang, Highly sensitive and simultaneous electrochemical determination of 2-aminophenol and 4-aminophenol based on poly(l-arginine)-β-cyclodextrin/carbon nanotubes@ graphene nanoribbons modified electrode, Biosens. and Bioelectron., 77 (2016) 353-358.
G. Zhang, P. He, W. Feng, S. Ding, J. Chen, L. Li, H. He, S. Zhang, F. Dong, Carbon nanohorns/poly(glycine) modified glassy carbon electrode: Preparation, characterization and simultaneous electrochemical determination of uric acid, dopamine and ascorbic acid, J. Electroanal. Chem., 760 (2016) 24-31.
F. Zhang, S. Gu, Y. Ding, L. Zhou, Z. Zhang, L. Li, Electrooxidation and determination of cefotaxime on Au nanoparticles/poly (L-arginine) modified carbon paste electrode, J. Electroanal. Chem., 698 (2013) 30. CC 92 26 60 57 22 53 05 32 18 26 72 30

Altın Nanopartikül ve Poli arjinin Modifiye Camsı Karbon Elektrot ile Hidrokinon ve Katekolün Eş Zamanlı Tayini

Yıl 2017, Cilt: 45 Sayı: 3, 443 - 451, 01.09.2017

Gözde Aydoğdu Tığ

Öz

B u çalışmada, hidrokinon HQ ve katekolün CC tayini için altın nanopartikül AuNP ve poli L-arjinin P AG modifiye edilmiş camsı karbon elektrot GCE P AG /AuNP/GCE temelli yeni bir elektrokimyasal sensör tasarlandı. Taramalı elektron mikroskobu SEM , dönüşümlü voltametri DV ve elektrokimyasal impedans spektroskopisi EİS P AG /AuNP/GCE’yi karakterize etmek için kullanıldı. Diferansiyel puls voltametrisi sonuçları modifiye elektrodun hidrokinon ve katekolün eş zamanlı tayini için yüksek duyarlılık ve hassasiyet gösterdi. HQ ve CC’nin doğrusal çalışma aralığı 5.0 ile 600.0 µmol L-1 arasında ve gözlenebilme sınırları sırasıyla 1.5 ve 1.42 µmol L-1 olarak bulundu. Hazırlanan sensör hidrokinon ve katekolün gerçek örneklerde hızlı analizi için yüksek geri kazanımla düşük maliyetli uygun bir araç olarak önerildi. Hazırlanan sensör, yüksek geri kazanımlarla gerçek numunelerde HQ ve CC’nin hızlı analizi için düşük maliyetli uygun bir araçtır

Anahtar Kelimeler

Hidrokinon, katekol, eş zamanlı, poly arjinin, AuNP

Kaynakça

Y. Wang, J. Qu, S. Li, Y. Dong, J. Qu, Simultaneous determination of hydroquinone and catechol using a glassy carbon electrode modified with gold nanoparticles, ZnS/NiS@ZnS quantum dots and L-cysteine, Microchim. Acta, 182 (2015) 2277-2283.
P. Nagaraja, R.A. Vasantha, K.R. Sunitha, A sensitive and selective spectrophotometric estimation of catechol derivatives in pharmaceutical preparations, Talanta, 55 (2001) 1039-1046.
G. Marrubini, E. Calleri, T. Coccini, A.F. Castoldi, L. Manzo, Direct Analysis of Phenol, Catechol and Hydroquinone in Human Urine by Coupled-Column HPLC with Fluorimetric Detection, Chromatographia, (2005) 25-31.
M.F. Pistonesi, M.S. Di Nezio, M.E. Centurión, M.E. Palomeque, A.G. Lista, B.S. Fernández Band, Determination of phenol, resorcinol and hydroquinone in air samples by synchronous fluorescence using partial least-squares (PLS), Talanta, 69 (2006) 1265
B. Unnikrishnan, P.-L. Ru, S.-M. Chen, Electrochemically synthesized Pt–MnO2 composite particles for simultaneous determination of catechol and hydroquinone, Sens. Actuat. B: Chem., 169 (2012) 242.
Z. Guo, Y. Lu, J. Li, X.-f. Xu, G.-q. Huang, Z.-y. Wang, catechol using an electrode modified by a composite of graphene/lanthanum hydroxide nanowires, Anal. Methods, 6 (2014) 8314-8320.
W. Si, W. Lei, Y. Zhang, M. Xia, F. Wang, Q. Hao, Electrodeposition of graphene oxide doped poly(3,4- ethylenedioxythiophene) film and its electrochemical sensing of catechol and hydroquinone, Electrochim. Acta, 85 (2012) 295-301.
D.P. Santos, M.F. Bergamini, A.G. Fogg, M.V.B. Zanoni, Application of a Glassy Carbon Electrode Modified with Poly(Glutamic Acid) in Caffeic Acid Determination, Microchim. Acta, 151 (2005) 127-134.
K. Zhang, P. Luo, J. Wu, W. Wang, B. Ye, Highly sensitive determination of Sunset Yellow in drink using a poly (l-cysteine) modified glassy carbon electrode, Anal. Methods, 5 (2013) 5044-5050.
Z. Guo, G.-q. Huang, J. Li, Z.-y. Wang, X.-f. Xu, Graphene oxide-Ag/poly-l-lysine modified glassy carbon electrode as an electrochemical sensor for the determination of dopamine in the presence of ascorbic acid, J. Electroanal. Chem., 759, Part 2 (2015) 113-121.
Y. Yi, G. Zhu, X. Wu, K. Wang, Highly sensitive and simultaneous electrochemical determination of 2-aminophenol and 4-aminophenol based on poly(l-arginine)-β-cyclodextrin/carbon nanotubes@ graphene nanoribbons modified electrode, Biosens. and Bioelectron., 77 (2016) 353-358.
G. Zhang, P. He, W. Feng, S. Ding, J. Chen, L. Li, H. He, S. Zhang, F. Dong, Carbon nanohorns/poly(glycine) modified glassy carbon electrode: Preparation, characterization and simultaneous electrochemical determination of uric acid, dopamine and ascorbic acid, J. Electroanal. Chem., 760 (2016) 24-31.
F. Zhang, S. Gu, Y. Ding, L. Zhou, Z. Zhang, L. Li, Electrooxidation and determination of cefotaxime on Au nanoparticles/poly (L-arginine) modified carbon paste electrode, J. Electroanal. Chem., 698 (2013) 30. CC 92 26 60 57 22 53 05 32 18 26 72 30

Toplam 13 adet kaynakça vardır.

Ayrıntılar

Birincil Dil	İngilizce
Bölüm	Research Article
Yazarlar	Gözde Aydoğdu Tığ
Yayımlanma Tarihi	1 Eylül 2017
Yayımlandığı Sayı	Yıl 2017 Cilt: 45 Sayı: 3

Kaynak Göster

APA	Aydoğdu Tığ, G. (2017). Gold Nanoparticle and Poly Arginine Modified GCE for Simultaneous Determination of Hydroquinone and Catechol. Hacettepe Journal of Biology and Chemistry, 45(3), 443-451.
AMA	Aydoğdu Tığ G. Gold Nanoparticle and Poly Arginine Modified GCE for Simultaneous Determination of Hydroquinone and Catechol. HJBC. Eylül 2017;45(3):443-451.
Chicago	Aydoğdu Tığ, Gözde. “Gold Nanoparticle and Poly Arginine Modified GCE for Simultaneous Determination of Hydroquinone and Catechol”. Hacettepe Journal of Biology and Chemistry 45, sy. 3 (Eylül 2017): 443-51.
EndNote	Aydoğdu Tığ G (01 Eylül 2017) Gold Nanoparticle and Poly Arginine Modified GCE for Simultaneous Determination of Hydroquinone and Catechol. Hacettepe Journal of Biology and Chemistry 45 3 443–451.
IEEE	G. Aydoğdu Tığ, “Gold Nanoparticle and Poly Arginine Modified GCE for Simultaneous Determination of Hydroquinone and Catechol”, HJBC, c. 45, sy. 3, ss. 443–451, 2017.
ISNAD	Aydoğdu Tığ, Gözde. “Gold Nanoparticle and Poly Arginine Modified GCE for Simultaneous Determination of Hydroquinone and Catechol”. Hacettepe Journal of Biology and Chemistry 45/3 (Eylül 2017), 443-451.
JAMA	Aydoğdu Tığ G. Gold Nanoparticle and Poly Arginine Modified GCE for Simultaneous Determination of Hydroquinone and Catechol. HJBC. 2017;45:443–451.
MLA	Aydoğdu Tığ, Gözde. “Gold Nanoparticle and Poly Arginine Modified GCE for Simultaneous Determination of Hydroquinone and Catechol”. Hacettepe Journal of Biology and Chemistry, c. 45, sy. 3, 2017, ss. 443-51.
Vancouver	Aydoğdu Tığ G. Gold Nanoparticle and Poly Arginine Modified GCE for Simultaneous Determination of Hydroquinone and Catechol. HJBC. 2017;45(3):443-51.