Araştırma Makalesi
Yıl 2025,
Cilt: 13 Sayı: 2, 445 - 458, 01.06.2025
Öz
Kaynakça
- Malara, A., “Environmental concerns on the use of the electrospinning technique for the production of polymeric micro/nanofibers”, Scientific Reports, 14(1):8293, 2024.
- Mowafi, S. and H. El-Sayed, “Production and utilization of keratin and sericin-based electro-spun nanofibers: A comprehensive review”, Journal of Natural Fibers, 20(1):2192544, 2023.
- Habis, C., et al., “Specific role of Al in the synthesis of electrospun Al: ZnO nanofibers: Thermal and elemental analysis”, Materials Today Communications, 38:108196, 2024.
- Wali, A., et al., “Silver nanoparticles in electrospun ethyl hydroxy ethyl cellulose-PVA Nanofiber: Synthesis, characterization and wound dressing applications”, Carbohydrate Polymer Technologies and Applications, 7:100477, 2024.
- George, N., et al., “Incorporating silver nanoparticles into electrospun nanofibers of casein/polyvinyl alcohol to develop scaffolds for tissue engineering”, International Journal of Biological Macromolecules, 131501, 2024.
- Khaleel, M.R., F.S. Hashim, and A.H.O. Alkhayatt, “Preparation, characterization, and the antimicrobial activity of PVA-PVP/ZnO nanofiber films via indigenous electrospinning setup”, Journal of Molecular Structure, 138325, 2024.
- Krishna, K., et al., “Fabrication and conductivity study of silver nanoparticles loaded polyvinyl alcohol (PVA-AgNPs) nanofibers”, Materials Today: Proceedings, 42:515-520, 2021.
- Wang, Y., et al., “PEM Fuel cell and electrolysis cell technologies and hydrogen infrastructure development–a review”, Energy & Environmental Science, 15(6):2288-2328, 2022.
- Abdelkareem, M.A., et al., “Environmental aspects of fuel cells: A review”, Science of The Total Environment, 752:141803, 2021.
- Sharma, S., S. Agarwal, and A. Jain, “Significance of hydrogen as economic and environmentally friendly fuel”, Energies, 14(21):7389, 2021.
- Patil, V., et al., “Degradation mechanisms in PEM fuel cells: A brief review”, Materials Today: Proceedings, 2023.
- Karanfil, G., “Importance and applications of DOE/optimization methods in PEM fuel cells: A review”, International Journal of Energy Research, 44(1):4-25, 2020.
- Singh, R., A.S. Oberoi, and T. Singh, “Heat pipes for PEM fuel cell cooling: State of the art review”, Materials Today: Proceedings, 2023.
- Datta, A., “PEM Fuel Cell MODEL for conceptual design of hydrogen eVTOL aircraft”, 2021.
- Ormsby, S., “Modelling and design of PEM fuel cell electric military armoured vehicles using a new real-world operation profile model”, 2021.
- Athanasaki, G., A. Jayakumar, and A. Kannan, “Gas diffusion layers for PEM fuel cells: Materials, properties and manufacturing–A review”, International Journal of Hydrogen Energy, 48(6):2294-2313, 2023.
- Yanilmaz, M., et al., “Centrifugally spun PVA/PVP based B, N, F doped carbon nanofiber electrodes for sodium ion batteries”, Polymers, 14(24):5541, 2022.
- Yoon, H., et al., “Adaptive Epidermal Bioelectronics by Highly Breathable and Stretchable Metal Nanowire Bioelectrodes on Electrospun Nanofiber Membrane”, Advanced Functional Materials, 2313504, 2024.
- Sakthivel, P., et al., “Low content of Ni‐Pt nanoparticles decorated carbon nanofibers as efficient electrocatalyst for hydrogen evolution reaction”, Journal of Chemical Technology & Biotechnology, 2024.
- Yu, H., M. Zhang, and T. Jin, “Electrospun Ag/TiO2 Heterostructured Nanofibers for Photoelectrochemical Applications”, Russian Journal of Physical Chemistry A, 97(12):2786-2791, 2023.
- Wang, C., et al., “Controllable growth of silver nanoparticles on titanium dioxide/nitrogen-doped carbon nanofiber/molybdenum disulfide: Toward enhanced photocatalytic-activating peroxymonosulfate performance and “memory catalysis””, Chemical Engineering Journal, 479: 147752, 2024.
- Gao, M., et al., “Flexible nitrogen-doped carbon nanofiber-reinforced hierarchical hollow iron oxide nanorods as a binder-free electrode for efficient capacitive deionization”, Desalination, 549:116360, 2023.
- Sharma, G.K. and N.R. James, “Flexible N-doped carbon nanofiber-polydimethylsiloxane composite containing La0. 85Sr0. 15CoO3− δ nanoparticles for green EMI shielding”, ACS Applied Nano Materials, 6(7):6024-6035, 2023.
- Guan, J., et al., “Integrating RuCo alloy in N-doped carbon nanofiber for efficient hydrogen evolution in alkaline media”, Journal of Alloys and Compounds, 942:168941, 2023.
- Chen, F., et al., “Hierarchical N-doped carbon nanofiber-loaded NiCo alloy nanocrystals with enhanced methanol electrooxidation for alkaline direct methanol fuel cells”, Journal of Colloid and Interface Science, 646:43-53, 2023.
- Yang, T., et al., “Oxygen-doped carbon nanofiber nonwovens as an effective interlayer towards accelerating electrochemical kinetics for lithium-sulfur battery”, Applied Surface Science, 611:155690, 2023.
- Wang, F., et al., “Sulfur doped hollow carbon nanofiber anodes for fast-charging potassium-ion storage”, Applied Surface Science, 614:156149, 2023.
- Zhang, L., et al., “Rapid quantitative detection of luteolin using an electrochemical sensor based on electrospinning of carbon nanofibers doped with single-walled carbon nanoangles”, Analytical Methods, 15(25):3073-3083, 2023.
Yıl 2025,
Cilt: 13 Sayı: 2, 445 - 458, 01.06.2025
Öz
PVA nanofiber materials are widely utilized in energy applications, particularly in PEM fuel cells. In this study, Ag- and Pt-doped PVA nanofibers were fabricated via the electrospinning method at different weight ratios and compared with pure PVA nanofibers. The thermal and electrical conductivities, PEM fuel cell performances, and morphological structures of the nanofibers were investigated. The results demonstrated that the highest electrical conductivity (16.80 S/cm) was achieved with the addition of 5% Ag nanoparticles, while Pt nanoparticle doping also improved electrical conductivity but to a lesser extent (14.90 S/cm). In terms of thermal conductivity, Ag nanoparticle doping increased the Thermal Conductivity Coefficient by approximately 28%, whereas Pt nanoparticle doping had the opposite effect, reducing it by 43%. Additionally, the hydrophilicity of the nanofibers increased with increasing nanoparticle content. The PEM fuel cell tests indicated that Ag-doped PVA nanofibers exhibited superior performance compared to pure PVA nanofibers, making them a promising material for energy applications.
Anahtar Kelimeler
PEM Fuel Cell PVA Nanofiber Design of Experiment Nanoparticle
Kaynakça
- Malara, A., “Environmental concerns on the use of the electrospinning technique for the production of polymeric micro/nanofibers”, Scientific Reports, 14(1):8293, 2024.
- Mowafi, S. and H. El-Sayed, “Production and utilization of keratin and sericin-based electro-spun nanofibers: A comprehensive review”, Journal of Natural Fibers, 20(1):2192544, 2023.
- Habis, C., et al., “Specific role of Al in the synthesis of electrospun Al: ZnO nanofibers: Thermal and elemental analysis”, Materials Today Communications, 38:108196, 2024.
- Wali, A., et al., “Silver nanoparticles in electrospun ethyl hydroxy ethyl cellulose-PVA Nanofiber: Synthesis, characterization and wound dressing applications”, Carbohydrate Polymer Technologies and Applications, 7:100477, 2024.
- George, N., et al., “Incorporating silver nanoparticles into electrospun nanofibers of casein/polyvinyl alcohol to develop scaffolds for tissue engineering”, International Journal of Biological Macromolecules, 131501, 2024.
- Khaleel, M.R., F.S. Hashim, and A.H.O. Alkhayatt, “Preparation, characterization, and the antimicrobial activity of PVA-PVP/ZnO nanofiber films via indigenous electrospinning setup”, Journal of Molecular Structure, 138325, 2024.
- Krishna, K., et al., “Fabrication and conductivity study of silver nanoparticles loaded polyvinyl alcohol (PVA-AgNPs) nanofibers”, Materials Today: Proceedings, 42:515-520, 2021.
- Wang, Y., et al., “PEM Fuel cell and electrolysis cell technologies and hydrogen infrastructure development–a review”, Energy & Environmental Science, 15(6):2288-2328, 2022.
- Abdelkareem, M.A., et al., “Environmental aspects of fuel cells: A review”, Science of The Total Environment, 752:141803, 2021.
- Sharma, S., S. Agarwal, and A. Jain, “Significance of hydrogen as economic and environmentally friendly fuel”, Energies, 14(21):7389, 2021.
- Patil, V., et al., “Degradation mechanisms in PEM fuel cells: A brief review”, Materials Today: Proceedings, 2023.
- Karanfil, G., “Importance and applications of DOE/optimization methods in PEM fuel cells: A review”, International Journal of Energy Research, 44(1):4-25, 2020.
- Singh, R., A.S. Oberoi, and T. Singh, “Heat pipes for PEM fuel cell cooling: State of the art review”, Materials Today: Proceedings, 2023.
- Datta, A., “PEM Fuel Cell MODEL for conceptual design of hydrogen eVTOL aircraft”, 2021.
- Ormsby, S., “Modelling and design of PEM fuel cell electric military armoured vehicles using a new real-world operation profile model”, 2021.
- Athanasaki, G., A. Jayakumar, and A. Kannan, “Gas diffusion layers for PEM fuel cells: Materials, properties and manufacturing–A review”, International Journal of Hydrogen Energy, 48(6):2294-2313, 2023.
- Yanilmaz, M., et al., “Centrifugally spun PVA/PVP based B, N, F doped carbon nanofiber electrodes for sodium ion batteries”, Polymers, 14(24):5541, 2022.
- Yoon, H., et al., “Adaptive Epidermal Bioelectronics by Highly Breathable and Stretchable Metal Nanowire Bioelectrodes on Electrospun Nanofiber Membrane”, Advanced Functional Materials, 2313504, 2024.
- Sakthivel, P., et al., “Low content of Ni‐Pt nanoparticles decorated carbon nanofibers as efficient electrocatalyst for hydrogen evolution reaction”, Journal of Chemical Technology & Biotechnology, 2024.
- Yu, H., M. Zhang, and T. Jin, “Electrospun Ag/TiO2 Heterostructured Nanofibers for Photoelectrochemical Applications”, Russian Journal of Physical Chemistry A, 97(12):2786-2791, 2023.
- Wang, C., et al., “Controllable growth of silver nanoparticles on titanium dioxide/nitrogen-doped carbon nanofiber/molybdenum disulfide: Toward enhanced photocatalytic-activating peroxymonosulfate performance and “memory catalysis””, Chemical Engineering Journal, 479: 147752, 2024.
- Gao, M., et al., “Flexible nitrogen-doped carbon nanofiber-reinforced hierarchical hollow iron oxide nanorods as a binder-free electrode for efficient capacitive deionization”, Desalination, 549:116360, 2023.
- Sharma, G.K. and N.R. James, “Flexible N-doped carbon nanofiber-polydimethylsiloxane composite containing La0. 85Sr0. 15CoO3− δ nanoparticles for green EMI shielding”, ACS Applied Nano Materials, 6(7):6024-6035, 2023.
- Guan, J., et al., “Integrating RuCo alloy in N-doped carbon nanofiber for efficient hydrogen evolution in alkaline media”, Journal of Alloys and Compounds, 942:168941, 2023.
- Chen, F., et al., “Hierarchical N-doped carbon nanofiber-loaded NiCo alloy nanocrystals with enhanced methanol electrooxidation for alkaline direct methanol fuel cells”, Journal of Colloid and Interface Science, 646:43-53, 2023.
- Yang, T., et al., “Oxygen-doped carbon nanofiber nonwovens as an effective interlayer towards accelerating electrochemical kinetics for lithium-sulfur battery”, Applied Surface Science, 611:155690, 2023.
- Wang, F., et al., “Sulfur doped hollow carbon nanofiber anodes for fast-charging potassium-ion storage”, Applied Surface Science, 614:156149, 2023.
- Zhang, L., et al., “Rapid quantitative detection of luteolin using an electrochemical sensor based on electrospinning of carbon nanofibers doped with single-walled carbon nanoangles”, Analytical Methods, 15(25):3073-3083, 2023.
Toplam 28 adet kaynakça vardır.
Ayrıntılar
| Birincil Dil | İngilizce |
|---|---|
| Konular | Malzeme Bilimi ve Teknolojileri, Enerji Üretimi, Dönüşüm ve Depolama (Kimyasal ve Elektiksel hariç), Malzeme Tasarım ve Davranışları |
| Bölüm | Araştırma Makalesi |
| Yazarlar | |
| Yayımlanma Tarihi | 1 Haziran 2025 |
| Gönderilme Tarihi | 28 Aralık 2024 |
| Kabul Tarihi | 16 Mart 2025 |
| Yayımlandığı Sayı | Yıl 2025 Cilt: 13 Sayı: 2 |
