Öz
Bu çalışmada, grafen kaplı Langmuir-Blodgett (LB) ince filmlerin şişme davranışları Kuartz Kristal Mikrobalans (KKM) tekniği kullanılarak incelenmiştir. Bu filmler, bazı organik buharların (aseton, etanol ve metanol) difüzyon katsayı değerlerinin hesaplanması (Fick’in erken-zaman difüzyon kanunu kullanılarak) için oda sıcaklığında etkileşmeye bırakılmıştır. Difüzyon katsayı değerleri sırası ile aseton, etanol ve metanol için 20.43 x 10−16, 1.30 x 10−16 ve 0.91 x 10−16 cm2 s−1 olarak hesaplanmıştır. Benzer sıralama grafen kaplı KKM sensörünün tepkisi (frekans değişimi, Δf) için de aseton (342 Hz) > etanol (76 Hz) > metanol (51 Hz) olarak elde edilmiştir.
Anahtar Kelimeler
kuartz kristal mikrobalans grafen kimyasal sensör matematiksel modelleme
Kaynakça
- Botcha V.D, P.K. Narayanam, G. Singh, S.S. Talwar, R.S. Srinivasa, S.S. Major, (2014). Colloids Surf. A Physicochem. Eng. Asp. 452, 65
- Cai W, S. Jiang, S. Xu, Y.Li, J.Liu, C. Li, L. Zheng, L. Su, J. Xu, (2015).Opt. Laser Techno. 65, 1.
- Capan I, C. Tarımcı, R. Capan, (2010). Sens. Actuators B: Chem. 144, 126.
- Crank J, (1970). The Mathematics of Diffusion, Oxford University Press, London
- Liu Q, Z. F. Liu, X. Y. Zhang, N. Zhang, L. Y. Yang, S. G. Yin, Y. S. Chen, (2008). Appl. Phys. Lett. 92, 223303
- Quang V.V, V.N. Hung, L.A. Tuan, V.N. Phan, T. Q. Huy, N.V. Quy, (2014). Thin Solid Films 568, 6.
- Sauerbrey G, Verwendung von schwingquarzen zur wägung dünner schichten und zur microwägung, (1959) Z. Phys. 155, 206-222.
- Seger B, P. V. Kamat, (2009). J. Phys. Chem. C 113, 7990.
- Yao Y, X. Chen, H. Guo, Z. Wu, (2011). Appl. Surf. Sci. 257, 7778.
- Yao Y, X. Chen, X. Li, X. Chen, N. Li, (2014). Sens. Actuators B: Chem. 191, 779.
- Zhang H, G. Grüner, Y. Zhao, (2013). J. Mater. Chem. B 1, 2542
- Zhang Y, L. Du, Y. Lei, H. Zhao, (2014). Mater. Lett. 131, 288
- Zhihua Y, Z. Liang, S. Kaixin, H. Weiwei, (2012). Procedia Eng. 29, 2448.
- Zhu Z, Min Su, L. Ma, L. Ma, D. Liu, Z. Wang, (2013). Talanta 117, 449.
Öz
In this work, the swelling behaviors of the graphene-coated Langmuir-Blodgett (LB) thin films are investigated by using Quartz Crystal Microbalance (QCM) technique. These films were exposed to several Volatile Organic Compounds (VOCs) (acetone, ethanol and methanol) at room temperature to calculate diffusion coefficients of these organic vapors by using the early-time Fick’s law of diffusion. The diffusion coefficients are calculated to be 20.43 x 10−16, 1.30 x 10−16 and 0.91 x 10−16 cm2 s−1 for acetone, ethanol and methanol, respectively. Similar ranking was obtained for the response of graphene-coated QCM sensor as a frequency shift (Δf); acetone (342 Hz) > ethanol (76 Hz) > methanol (51 Hz).
Anahtar Kelimeler
Quartz crystal microbalance graphene chemical sensor mathematical modelling
Kaynakça
- Botcha V.D, P.K. Narayanam, G. Singh, S.S. Talwar, R.S. Srinivasa, S.S. Major, (2014). Colloids Surf. A Physicochem. Eng. Asp. 452, 65
- Cai W, S. Jiang, S. Xu, Y.Li, J.Liu, C. Li, L. Zheng, L. Su, J. Xu, (2015).Opt. Laser Techno. 65, 1.
- Capan I, C. Tarımcı, R. Capan, (2010). Sens. Actuators B: Chem. 144, 126.
- Crank J, (1970). The Mathematics of Diffusion, Oxford University Press, London
- Liu Q, Z. F. Liu, X. Y. Zhang, N. Zhang, L. Y. Yang, S. G. Yin, Y. S. Chen, (2008). Appl. Phys. Lett. 92, 223303
- Quang V.V, V.N. Hung, L.A. Tuan, V.N. Phan, T. Q. Huy, N.V. Quy, (2014). Thin Solid Films 568, 6.
- Sauerbrey G, Verwendung von schwingquarzen zur wägung dünner schichten und zur microwägung, (1959) Z. Phys. 155, 206-222.
- Seger B, P. V. Kamat, (2009). J. Phys. Chem. C 113, 7990.
- Yao Y, X. Chen, H. Guo, Z. Wu, (2011). Appl. Surf. Sci. 257, 7778.
- Yao Y, X. Chen, X. Li, X. Chen, N. Li, (2014). Sens. Actuators B: Chem. 191, 779.
- Zhang H, G. Grüner, Y. Zhao, (2013). J. Mater. Chem. B 1, 2542
- Zhang Y, L. Du, Y. Lei, H. Zhao, (2014). Mater. Lett. 131, 288
- Zhihua Y, Z. Liang, S. Kaixin, H. Weiwei, (2012). Procedia Eng. 29, 2448.
- Zhu Z, Min Su, L. Ma, L. Ma, D. Liu, Z. Wang, (2013). Talanta 117, 449.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Bölüm | Araştırma Makaleleri |
| Yazarlar | |
| Yayımlanma Tarihi | 31 Ekim 2020 |
| Gönderilme Tarihi | 7 Ekim 2020 |
| Yayımlandığı Sayı | Yıl 2020 Cilt: 46 Sayı: 2 |
Kaynak Göster
Journal Owner: On behalf of Selçuk University Faculty of Science, Rector Prof. Dr. Hüseyin YILMAZ
Selcuk University Journal of Science Faculty accepts articles in Turkish and English with original results in basic sciences and other applied sciences. The journal may also include compilations containing current innovations.
It was first published in 1981 as "S.Ü. Fen-Edebiyat Fakültesi Dergisi" and was published under this name until 1984 (Number 1-4).
In 1984, its name was changed to "S.Ü. Fen-Edeb. Fak. Fen Dergisi" and it was published under this name as of the 5th issue.
When the Faculty of Letters and Sciences was separated into the Faculty of Science and the Faculty of Letters with the decision of the Council of Ministers numbered 2008/4344 published in the Official Gazette dated 3 December 2008 and numbered 27073, it has been published as "Selcuk University Journal of Science Faculty" between 2009-2025.
It has been scanned in DergiPark since 2016.
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