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Kozalak Sapı tozu kullanarak sulu çözeltilerden Telon Blue Boyası adsorpsiyonu: İzoterm, Kinetik modelleri ve adsorpsiyon ısısı

Yıl 2025, Cilt: 31 Sayı: 3, 417 - 427, 30.06.2025

Melike İşgören

Öz

Bu çalışmada, doğada kolayca bulunabilen ağaç kozalak saplarının tozu (KST) kullanılarak sulu çözeltilerden Telon Blue (TB) boyası giderimi araştırılmıştır. TB giderimini etkileyen faktörleri belirleyebilmek için pH (3-11), kozalak miktarı (3-10 g/L), karıştırma hızı (50-250 rpm), temas süresi (5-90 dk., başlangıç boya konsantrasyonu (25-400 mg/L) ve sıcaklık (25-55 °C) parametreleri incelenmiştir. Adsorpsiyon prosesi üzerine pH etkisinin değerlendirilebilmesi için KST ye ait izoelektrik nokta tayini (pHpzc) değeri pH drift metodu kullanılarak, 5.4 olarak bulunmuştur. Deneysel çalışmalar sonunda %87.6’lık maksimum boya giderim verimi pH 3’te, 5 g/L adsorbent dozu, 200 rpm karıştırma hızı, 10 dk. temas süresi ve 25° sıcaklık değerlerinde elde edilmiştir. Adsorpsiyon mekanizmasının anlaşılabilmesi için kinetik ve izoterm modelleri ile incelenmiş sözde ikinci derece kinetik (𝑅2=0.99) ve Temkin izoterm modellerine (𝑅2=0.97) daha uyumlu olduğu görülmüştür. Termodinamik çalışmalar sonucunda 𝛥𝐻°'ın negatif değeri adsorpsiyon prosesinin ekzotermik olduğunu göstermektedir. KST’nin boya karışımından TB’yi yüksek oranda adsorpladığı yapılan deney ile kanıtlanmıştır. Çalışma, KST'nin TB boyasını sulu çözeltilerden uzaklaştırmada etkili ve tekrar kullanılabilirliği yüksek bir adsorbent olduğunu ortaya koymuştur.

Anahtar Kelimeler

Adsorpsiyon kozalak sapı Adsorpsiyon kinetiği Adsorpsiyon izotermleri Adsorpsiyon termodinamiği İzoelektrik nokta

Kaynakça

  • [1] Gümüş D, Gümüş F. "The use of a wetland plant as a new biosorbent for treatment of water contaminated with heavy metals: Nonlinear analyses, modification, competitive effects". Environmental Technology and Innovation, 16, 100483, 2019.
  • [2] Bansal S, Pandey PK, Upadhayay S. "Methylene Blue Dye removal from wastewater using Ailanthus Excelsa Roxb as adsorbent". Water Conservation Science and Engineering, 6(1), 1-9, 2021.
  • [3] Dawood S, Sen TK. "Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: Equilibrium, thermodynamic, kinetics, mechanism and process design". Water Research, 46(6),1933-1946, 2012.
  • [4] de la Luz-Asunción M, Pérez-Ramírez EE, MartínezHernández AL, García-Casillas PE, Luna-Bárcenas JG, Velasco-Santos C. "Adsorption and kinetic study of Reactive Red 2 dye onto graphene oxides and graphene quantum dots". Diamond and Related Materials, 109, 108002, 2020.
  • [5] Salleh MAM, Mahmoud DK, Karim WAWA, Idris A. "Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review". Desalination, 280(1-3), 1-13, 2011.
  • [6] Makhoukhi B, Djab M, Amine Didi M. "Adsorption of Telon dyes onto bis-imidazolium modified bentonite in aqueous solutions". Journal of Environmental Chemical Engineering, 3(2), 1384-1392, 2015.
  • [7] Amar IA, Zayid EA, Dhikeel SA, Najem MY. "Biosorption removal of methylene blue dye from aqueous solutions using phosphoric acid-treated balanites aegyptiaca seed husks powder". Biointerface Research in Applied Chemistry, 212(6), 7845-7862, 2022.
  • [8] Sulak MT, Demirbas E, Kobya M. "Removal of Astrazon Yellow 7GL from aqueous solutions by adsorption onto wheat bran". Bioresource Technology, 98(13), 2590-2598, 2007.
  • [9] Sezer M, Gulumser Goktas C, Isgoren M, Veli S, Bingol SN, Cakmak IN. "Response surface optimization of electrocoagulation for the removal of C.I. Disperse Red 343 and Isolan Bordeaux 2S-B dyes". Desalination and Water Treatment, 130622, 2024.
  • [10] Liang L, Shi X. "Electrochemical and photocatalytic properties of ZnO nanostructures deposited on nanoporous anodized aluminum oxide membrane and its application for degradation of reactive blue 19 in textile wastewater". International Journal of Electrochemical Science, 18(9), 100272, 2023.
  • [11] Hien SA, Trellu C, Oturan N, Assémian AS, Briton BGH, Drogui P, Adouby K, Oturam MA. "Comparison of homogeneous and heterogeneous electrochemical advanced oxidation processes for treatment of textile industry wastewater". Journal of Hazardous Materials, 437, 129326, 2022.
  • [12] Felista MM, Wanyonyi WC, Ongera G. "Adsorption of anionic dye (Reactive black 5) using macadamia seed Husks: Kinetics and equilibrium studies". Scientific African, 7, e00283, 2020.
  • [13] Ali ME, Hoque ME, Safdar Hossain SK, Biswas MC. "Nanoadsorbents for wastewater treatment: next generation biotechnological solution". International Journal of Environmental Science and Technology, 40954132, 2020.
  • [14] Kopaç T, Sulu E. "Bazik Kırmızı 46 Tekstil Boyasının Zonguldak Kömüründen Elde Edilen Farklı Aktif Karbonlar Üzerinde Adsorpsiyon Davranışının Karşılaştırılması". Gazi Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 34 (3), 1227-1240, 2019.
  • [15] Garg VK, Gupta R, Yadav AB, Kumar R. "Dye removal from aqueous solution by adsorption on treated sawdust". Bioresource Technology, 89(2), 121-124, 2003.
  • [16] Gül ÜD, Yıldız Y. "Yüzey aktif madde ile modifiye edilmiş atık yer fıstığı kabuğunun tekstil boyası biyosorpsiyonu kapasitesinin belirlenmesi". Türk Tarım ve Doğa Bilimleri Dergisi, 7(3), 533-539, 2020.
  • [17] AY Ç. "Kimyasal modifiye nar kabuğu ile anyonik boyanın biyosorpsiyonu: Modifikasyonun uzaklaştırma verimliliği üzerine etkisi". Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi, 18(2), 157-69, 2023.
  • [18] Sukmana H, Ballai G, Gyulavári T, Illés E, Kozma G, Kónya Z, Hodur C. “Hungarian and Indonesian rice husk as bioadsorbents for binary biosorption of cationic dyes from aqueous solutions: A factorial design analysis”. Heliyon, 9(6), e17154, 2023.
  • [19] Gören M, Murathan HB, Kaya N, Murathan AM. "Çam kozalağından üretilmiş modifiye aktif karbon ile sulu çözeltiden rodamin B boyasının adsorpsiyonu". Politeknik Dergisi, 26(1), 283-292, 2023.
  • [20] Bhomick PC, Supong A, Baruah M, Pongener C, Sinha D. "Pine Cone biomass as an efficient precursor for the synthesis of activated biocarbon for adsorption of anionic dye from aqueous solution: Isotherm, kinetic, thermodynamic and regeneration studies". Sustainable Chemistry and Pharmacy, 10, 41-9, 2018.
  • [21] Jari Y, Roche N, Chaker Necibi M, Zahra Falil F, Tayibi S, Lyamlouli K, Chehbouni A, Gourich B. "Porous activated carbons derived from waste Moroccan pine cones for high-performance adsorption of bisphenol A from water". Heliyon, 10(2024), e29645, 2024.
  • [22] Dawood S, Sen TK, Phan C. "Synthesis and characterization of slow pyrolysis pine cone bio-char in the removal of organic and inorganic pollutants from aqueous solution by adsorption: Kinetic, equilibrium, mechanism and thermodynamic". Bioresource Technology, 246, 76-81, 2017.
  • [23] Mahmoodi NM, Hayati B, Arami M, Lan C. "Adsorption of textile dyes on Pine Cone from colored wastewater: Kinetic, equilibrium and thermodynamic studies". Desalination, 268(1-3), 117-25, 2011.
  • [24] Makhoukhi B, Didi MA, Moulessehoul H, Azzouz A, Villemin D. "Diphosphonium ion-exchanged montmorillonite for Telon dye removal from aqueous media". Applied Clay Science, 50(3), 354-361, 2010.
  • [25] Rafatullah M, Sulaiman O, Hashim R, Ahmad A. "Adsorption of methylene blue on low-cost adsorbents: A review". Journal of Hazardous Materials, 177(1-3),70-80, 2010.
  • [26] Chen M, Wang X, Zhang H. "Comparative research on selective adsorption of Pb(II) by biosorbents prepared by two kinds of modifying waste biomass: Highly-efficient performance, application and mechanism". Journal of Environmental Management., 288:112388, 2021.
  • [27] Erkurt FE, Balcı B. "Reaktif black 5 boyar maddesinin aktif karbon üzerine adsorpsiyonunun kinetik ve adsorpsiyon modelleri kullanılarak incelenmesi". Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 30(1), 257-270, 2015.
  • [28] Eren Z, Acar Nuran F. "Uçucu kül adsorpsiyonu ile reaktif boya giderimi". Pamukkale Üniversitesi Mühendislik Fakültesi, 10(2), 253-258, 2024.
  • [29] Okur M, Aktı F, Çetintaş A. "Polianilin/Aljinat kompozit malzemesinin asit violet 90 boyar maddesinin gideriminde kullanılması: kinetik ve izoterm değerlendirmesi". Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji, 6(4), 729-740, 2018.
  • [30] Yönten V, Sanyürek NK, Kivanç MR. "A thermodynamic and kinetic approach to adsorption of methyl orange from aqueous solution using a low cost activated carbon prepared from Vitis vinifera L". Surfaces and Interfaces, 20, 1-8, 2020.
  • [31] Sh. Gohr M, Abd-Elhamid AI, El-Shanshory AA, Soliman HMA. "Adsorption of cationic dyes onto chemically modified activated carbon: Kinetics and thermodynamic study". Journal of Molecular Liquids, 346, 118227, 2022.
  • [32] Öter Ç. "Kromun zencefil tozu üzerine adsorpsiyon ile atık sulardan uzaklaştırılması". Nevşehir Bilim ve Teknoloji Dergisi, (9), 480-492, 2021.
  • [33] Önal Y, Tantekin T. "Aktif karbon, kil ve zeolit ile Malatya tekstil fabrikalarında kullanılan tekstil boyalarının adsorpsiyonu" Dicle Üniversitesi Mühendislik Fakültesi Dergisi, 9(2), 837-847, 2018.
  • [34] Kavci E, Erkmen J, Bingöl MS. "Removal of methylene blue dye from aqueous solution using citric acid modified apricot stone". Chemical Engineering Communications, 210(2), 165-80, 2023.
  • [35] De Rossi A, Rigueto CVT, Dettmer A, Colla LM, Piccin JS. "Synthesis, characterization, and application of Saccharomyces cerevisiae/alginate composites beads for adsorption of heavy metals". Journal of Environmental Chemical Engineering, 8(4), 104009, 2024.
  • [36] Arami M, Limaee NY, Mahmoodi NM, Tabrizi NS. "Removal of dyes from colored textile wastewater by orange peel adsorbent: Equilibrium and kinetic studies". Journal of Colloid and Interface Science, 288(2), 371-6, 2005.
  • [37] Mousa KM, Taha AH. "Adsorption of reactive blue dye onto natural and modified wheat straw". Journal of Chemical Engineering & Process Technology, 6(6), 1000260, 2015.
  • [38] Gönen F, Köylü E. "Environmental application of telon blue AGLF adsorption on sunflower pulp: A response surface methodology approach and kinetic study". Journal of Chemistry, 4, 1-10, 2016.
  • [39] Aksakal O, Ucun H. "Equilibrium, kinetic and thermodynamic studies of the biosorption of textile dye (Reactive Red 195) onto Pinus sylvestris L". Journal of Hazardous Materials, 181(1-3), 666-672, 2010.
  • [40] Tee WT, Loh NYL, Hiew BYZ, Chiu WS, Khiew PS, Thangalazhy-Gopakumar S, Gun S, Lee LY. "Design and development of a high-performance 3D graphene system for adsorptive removal of organic toxins from wastewater: Mechanisms and process optimization". Chemical Engineering Research and Design, 195, 132-50, 2023.
  • [41] Litefti K, Freire MS, Stitou M, González-Álvarez J. "Adsorption of an anionic dye (Congo red) from aqueous solutions by pine bark". Scientific Reports, 9(1), 1-11, 2019.
  • [42] Sen TK, Afroze S, Ang HM. “Equilibrium, kinetics and mechanism of removal of methylene blue from aqueous solution by adsorption onto pine cone biomass of Pinus radiata”. Water, Air, and Soil Pollution, 218, 499-515, 2011.
  • [43] Tanyıldızı MŞ, Uygut MA. "Çam Kozalağıyla Bazik Mavi 3Adsorpsiyonu". Fırat Üniversitesi Mühendislik Bilimleri Dergisi, 28(2), 169-74, 2016.
  • [44] Onursal N, Dal MC, Kul AR, Yavuz Ö. "CU(II) iyonlarının doğal karışık tipteki kil ile sulu ortamdan uzaklaştırılması, izoterm, kinetik ve termodinamik parametrelerin incelenmesi". Euroasia Journal of Mathematics, Engineering, Natural & Medical Sciences, 7(9), 85-103, 2020.
  • [45] Erdoğan FO. "Düşük maliyetli adsorbentler üzerine dispers sarı 211 tekstil boyasının adsorpsiyonu". Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi, 17, 889-898, 2017.
  • [46] Baytar O, Ceyhan AA, Şahin Ö. "İğde çekirdeğinden elde edilen aktif karbon kullanılarak kulu çözeltilerden Pb(II) adsorpsiyonun incelenmesi: İzoterm ve kinetik". Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, 7(2), 256-267, 2018.
  • [47] Sabar S, Abdul Aziz H, Yusof N H, Subramaniam S, Foo KY, Wilson L D, Lee H K. “Preparation of sulfonated chitosan for enhanced adsorption of methylene blue from aqueous solution”. Reactive and Functional Polymers, 151, 104584, 2020.
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Adsorption of Telon Blue Dye from aqueous solutions using pine cone powder: Isotherm, Kinetic models and heat of adsorption

Yıl 2025, Cilt: 31 Sayı: 3, 417 - 427, 30.06.2025

Melike İşgören

Öz

This study investigates the removal of Telon Blue (TB) dye from aqueous solutions using powder of tree cone stalks (KST), which is readily available in nature. The factors affecting TB removal, including pH (3-11), amount of adsorbent (3-10 g/L), stirring speed (50-250 rpm), contact time (5-90 min), initial dye concentration (25-400 mg/L), and temperature (25-55 °C), were examined. The pHpzc value of KST was determined using the pH drift method to evaluate the effect of pH on the adsorption process and found as 5.4. The 87.6% of maximum efficiency for dye removal was achieved under the following conditions: pH 3, 5 g/L of adsorbent, 200 rpm stirring speed, 10 minutes of contact time, and a temperature of 25 °C. To comprehend the adsorption mechanism, kinetic and isothermal models were applied and found to be more compatible with the pseudo-second-order (𝑅2=0.99) kinetic and Temkin (R2=0.99) isothermal models. The thermodynamic studies revealed that the adsorption process is exothermic, as indicated by the negative value of 𝛥𝐻°. It has been proven through experiments that KST absorbs TB from the dye mixture with high ratio. The study revealed that KST is an effective and highly reusable adsorbent in removing TB dye from aqueous solutions.

Anahtar Kelimeler

Adsorption cone stalk Adsorption kinetics Adsorption isotherms Adsorption thermodynamics Point of zero charge

Kaynakça

  • [1] Gümüş D, Gümüş F. "The use of a wetland plant as a new biosorbent for treatment of water contaminated with heavy metals: Nonlinear analyses, modification, competitive effects". Environmental Technology and Innovation, 16, 100483, 2019.
  • [2] Bansal S, Pandey PK, Upadhayay S. "Methylene Blue Dye removal from wastewater using Ailanthus Excelsa Roxb as adsorbent". Water Conservation Science and Engineering, 6(1), 1-9, 2021.
  • [3] Dawood S, Sen TK. "Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: Equilibrium, thermodynamic, kinetics, mechanism and process design". Water Research, 46(6),1933-1946, 2012.
  • [4] de la Luz-Asunción M, Pérez-Ramírez EE, MartínezHernández AL, García-Casillas PE, Luna-Bárcenas JG, Velasco-Santos C. "Adsorption and kinetic study of Reactive Red 2 dye onto graphene oxides and graphene quantum dots". Diamond and Related Materials, 109, 108002, 2020.
  • [5] Salleh MAM, Mahmoud DK, Karim WAWA, Idris A. "Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review". Desalination, 280(1-3), 1-13, 2011.
  • [6] Makhoukhi B, Djab M, Amine Didi M. "Adsorption of Telon dyes onto bis-imidazolium modified bentonite in aqueous solutions". Journal of Environmental Chemical Engineering, 3(2), 1384-1392, 2015.
  • [7] Amar IA, Zayid EA, Dhikeel SA, Najem MY. "Biosorption removal of methylene blue dye from aqueous solutions using phosphoric acid-treated balanites aegyptiaca seed husks powder". Biointerface Research in Applied Chemistry, 212(6), 7845-7862, 2022.
  • [8] Sulak MT, Demirbas E, Kobya M. "Removal of Astrazon Yellow 7GL from aqueous solutions by adsorption onto wheat bran". Bioresource Technology, 98(13), 2590-2598, 2007.
  • [9] Sezer M, Gulumser Goktas C, Isgoren M, Veli S, Bingol SN, Cakmak IN. "Response surface optimization of electrocoagulation for the removal of C.I. Disperse Red 343 and Isolan Bordeaux 2S-B dyes". Desalination and Water Treatment, 130622, 2024.
  • [10] Liang L, Shi X. "Electrochemical and photocatalytic properties of ZnO nanostructures deposited on nanoporous anodized aluminum oxide membrane and its application for degradation of reactive blue 19 in textile wastewater". International Journal of Electrochemical Science, 18(9), 100272, 2023.
  • [11] Hien SA, Trellu C, Oturan N, Assémian AS, Briton BGH, Drogui P, Adouby K, Oturam MA. "Comparison of homogeneous and heterogeneous electrochemical advanced oxidation processes for treatment of textile industry wastewater". Journal of Hazardous Materials, 437, 129326, 2022.
  • [12] Felista MM, Wanyonyi WC, Ongera G. "Adsorption of anionic dye (Reactive black 5) using macadamia seed Husks: Kinetics and equilibrium studies". Scientific African, 7, e00283, 2020.
  • [13] Ali ME, Hoque ME, Safdar Hossain SK, Biswas MC. "Nanoadsorbents for wastewater treatment: next generation biotechnological solution". International Journal of Environmental Science and Technology, 40954132, 2020.
  • [14] Kopaç T, Sulu E. "Bazik Kırmızı 46 Tekstil Boyasının Zonguldak Kömüründen Elde Edilen Farklı Aktif Karbonlar Üzerinde Adsorpsiyon Davranışının Karşılaştırılması". Gazi Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 34 (3), 1227-1240, 2019.
  • [15] Garg VK, Gupta R, Yadav AB, Kumar R. "Dye removal from aqueous solution by adsorption on treated sawdust". Bioresource Technology, 89(2), 121-124, 2003.
  • [16] Gül ÜD, Yıldız Y. "Yüzey aktif madde ile modifiye edilmiş atık yer fıstığı kabuğunun tekstil boyası biyosorpsiyonu kapasitesinin belirlenmesi". Türk Tarım ve Doğa Bilimleri Dergisi, 7(3), 533-539, 2020.
  • [17] AY Ç. "Kimyasal modifiye nar kabuğu ile anyonik boyanın biyosorpsiyonu: Modifikasyonun uzaklaştırma verimliliği üzerine etkisi". Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi, 18(2), 157-69, 2023.
  • [18] Sukmana H, Ballai G, Gyulavári T, Illés E, Kozma G, Kónya Z, Hodur C. “Hungarian and Indonesian rice husk as bioadsorbents for binary biosorption of cationic dyes from aqueous solutions: A factorial design analysis”. Heliyon, 9(6), e17154, 2023.
  • [19] Gören M, Murathan HB, Kaya N, Murathan AM. "Çam kozalağından üretilmiş modifiye aktif karbon ile sulu çözeltiden rodamin B boyasının adsorpsiyonu". Politeknik Dergisi, 26(1), 283-292, 2023.
  • [20] Bhomick PC, Supong A, Baruah M, Pongener C, Sinha D. "Pine Cone biomass as an efficient precursor for the synthesis of activated biocarbon for adsorption of anionic dye from aqueous solution: Isotherm, kinetic, thermodynamic and regeneration studies". Sustainable Chemistry and Pharmacy, 10, 41-9, 2018.
  • [21] Jari Y, Roche N, Chaker Necibi M, Zahra Falil F, Tayibi S, Lyamlouli K, Chehbouni A, Gourich B. "Porous activated carbons derived from waste Moroccan pine cones for high-performance adsorption of bisphenol A from water". Heliyon, 10(2024), e29645, 2024.
  • [22] Dawood S, Sen TK, Phan C. "Synthesis and characterization of slow pyrolysis pine cone bio-char in the removal of organic and inorganic pollutants from aqueous solution by adsorption: Kinetic, equilibrium, mechanism and thermodynamic". Bioresource Technology, 246, 76-81, 2017.
  • [23] Mahmoodi NM, Hayati B, Arami M, Lan C. "Adsorption of textile dyes on Pine Cone from colored wastewater: Kinetic, equilibrium and thermodynamic studies". Desalination, 268(1-3), 117-25, 2011.
  • [24] Makhoukhi B, Didi MA, Moulessehoul H, Azzouz A, Villemin D. "Diphosphonium ion-exchanged montmorillonite for Telon dye removal from aqueous media". Applied Clay Science, 50(3), 354-361, 2010.
  • [25] Rafatullah M, Sulaiman O, Hashim R, Ahmad A. "Adsorption of methylene blue on low-cost adsorbents: A review". Journal of Hazardous Materials, 177(1-3),70-80, 2010.
  • [26] Chen M, Wang X, Zhang H. "Comparative research on selective adsorption of Pb(II) by biosorbents prepared by two kinds of modifying waste biomass: Highly-efficient performance, application and mechanism". Journal of Environmental Management., 288:112388, 2021.
  • [27] Erkurt FE, Balcı B. "Reaktif black 5 boyar maddesinin aktif karbon üzerine adsorpsiyonunun kinetik ve adsorpsiyon modelleri kullanılarak incelenmesi". Çukurova Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, 30(1), 257-270, 2015.
  • [28] Eren Z, Acar Nuran F. "Uçucu kül adsorpsiyonu ile reaktif boya giderimi". Pamukkale Üniversitesi Mühendislik Fakültesi, 10(2), 253-258, 2024.
  • [29] Okur M, Aktı F, Çetintaş A. "Polianilin/Aljinat kompozit malzemesinin asit violet 90 boyar maddesinin gideriminde kullanılması: kinetik ve izoterm değerlendirmesi". Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji, 6(4), 729-740, 2018.
  • [30] Yönten V, Sanyürek NK, Kivanç MR. "A thermodynamic and kinetic approach to adsorption of methyl orange from aqueous solution using a low cost activated carbon prepared from Vitis vinifera L". Surfaces and Interfaces, 20, 1-8, 2020.
  • [31] Sh. Gohr M, Abd-Elhamid AI, El-Shanshory AA, Soliman HMA. "Adsorption of cationic dyes onto chemically modified activated carbon: Kinetics and thermodynamic study". Journal of Molecular Liquids, 346, 118227, 2022.
  • [32] Öter Ç. "Kromun zencefil tozu üzerine adsorpsiyon ile atık sulardan uzaklaştırılması". Nevşehir Bilim ve Teknoloji Dergisi, (9), 480-492, 2021.
  • [33] Önal Y, Tantekin T. "Aktif karbon, kil ve zeolit ile Malatya tekstil fabrikalarında kullanılan tekstil boyalarının adsorpsiyonu" Dicle Üniversitesi Mühendislik Fakültesi Dergisi, 9(2), 837-847, 2018.
  • [34] Kavci E, Erkmen J, Bingöl MS. "Removal of methylene blue dye from aqueous solution using citric acid modified apricot stone". Chemical Engineering Communications, 210(2), 165-80, 2023.
  • [35] De Rossi A, Rigueto CVT, Dettmer A, Colla LM, Piccin JS. "Synthesis, characterization, and application of Saccharomyces cerevisiae/alginate composites beads for adsorption of heavy metals". Journal of Environmental Chemical Engineering, 8(4), 104009, 2024.
  • [36] Arami M, Limaee NY, Mahmoodi NM, Tabrizi NS. "Removal of dyes from colored textile wastewater by orange peel adsorbent: Equilibrium and kinetic studies". Journal of Colloid and Interface Science, 288(2), 371-6, 2005.
  • [37] Mousa KM, Taha AH. "Adsorption of reactive blue dye onto natural and modified wheat straw". Journal of Chemical Engineering & Process Technology, 6(6), 1000260, 2015.
  • [38] Gönen F, Köylü E. "Environmental application of telon blue AGLF adsorption on sunflower pulp: A response surface methodology approach and kinetic study". Journal of Chemistry, 4, 1-10, 2016.
  • [39] Aksakal O, Ucun H. "Equilibrium, kinetic and thermodynamic studies of the biosorption of textile dye (Reactive Red 195) onto Pinus sylvestris L". Journal of Hazardous Materials, 181(1-3), 666-672, 2010.
  • [40] Tee WT, Loh NYL, Hiew BYZ, Chiu WS, Khiew PS, Thangalazhy-Gopakumar S, Gun S, Lee LY. "Design and development of a high-performance 3D graphene system for adsorptive removal of organic toxins from wastewater: Mechanisms and process optimization". Chemical Engineering Research and Design, 195, 132-50, 2023.
  • [41] Litefti K, Freire MS, Stitou M, González-Álvarez J. "Adsorption of an anionic dye (Congo red) from aqueous solutions by pine bark". Scientific Reports, 9(1), 1-11, 2019.
  • [42] Sen TK, Afroze S, Ang HM. “Equilibrium, kinetics and mechanism of removal of methylene blue from aqueous solution by adsorption onto pine cone biomass of Pinus radiata”. Water, Air, and Soil Pollution, 218, 499-515, 2011.
  • [43] Tanyıldızı MŞ, Uygut MA. "Çam Kozalağıyla Bazik Mavi 3Adsorpsiyonu". Fırat Üniversitesi Mühendislik Bilimleri Dergisi, 28(2), 169-74, 2016.
  • [44] Onursal N, Dal MC, Kul AR, Yavuz Ö. "CU(II) iyonlarının doğal karışık tipteki kil ile sulu ortamdan uzaklaştırılması, izoterm, kinetik ve termodinamik parametrelerin incelenmesi". Euroasia Journal of Mathematics, Engineering, Natural & Medical Sciences, 7(9), 85-103, 2020.
  • [45] Erdoğan FO. "Düşük maliyetli adsorbentler üzerine dispers sarı 211 tekstil boyasının adsorpsiyonu". Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi, 17, 889-898, 2017.
  • [46] Baytar O, Ceyhan AA, Şahin Ö. "İğde çekirdeğinden elde edilen aktif karbon kullanılarak kulu çözeltilerden Pb(II) adsorpsiyonun incelenmesi: İzoterm ve kinetik". Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, 7(2), 256-267, 2018.
  • [47] Sabar S, Abdul Aziz H, Yusof N H, Subramaniam S, Foo KY, Wilson L D, Lee H K. “Preparation of sulfonated chitosan for enhanced adsorption of methylene blue from aqueous solution”. Reactive and Functional Polymers, 151, 104584, 2020.
  • [48] Wójcik G, Hubicki Z. “Application of Pyrolox sorbent for vanadium (V) ions removal”. Physicochemical Problems of Mineral Processing, 58(2),147974, 2022.
Toplam 48 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Çevre Mühendisliği (Diğer)
Bölüm Makale
Yazarlar

Melike İşgören

Yayımlanma Tarihi 30 Haziran 2025
Gönderilme Tarihi 29 Şubat 2024
Kabul Tarihi 7 Ağustos 2024
Yayımlandığı Sayı Yıl 2025 Cilt: 31 Sayı: 3

Kaynak Göster

APA İşgören, M. (2025). Kozalak Sapı tozu kullanarak sulu çözeltilerden Telon Blue Boyası adsorpsiyonu: İzoterm, Kinetik modelleri ve adsorpsiyon ısısı. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 31(3), 417-427.
AMA İşgören M. Kozalak Sapı tozu kullanarak sulu çözeltilerden Telon Blue Boyası adsorpsiyonu: İzoterm, Kinetik modelleri ve adsorpsiyon ısısı. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. Haziran 2025;31(3):417-427.
Chicago İşgören, Melike. “Kozalak Sapı Tozu Kullanarak Sulu çözeltilerden Telon Blue Boyası Adsorpsiyonu: İzoterm, Kinetik Modelleri Ve Adsorpsiyon ısısı”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 31, sy. 3 (Haziran 2025): 417-27.
EndNote İşgören M (01 Haziran 2025) Kozalak Sapı tozu kullanarak sulu çözeltilerden Telon Blue Boyası adsorpsiyonu: İzoterm, Kinetik modelleri ve adsorpsiyon ısısı. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 31 3 417–427.
IEEE M. İşgören, “Kozalak Sapı tozu kullanarak sulu çözeltilerden Telon Blue Boyası adsorpsiyonu: İzoterm, Kinetik modelleri ve adsorpsiyon ısısı”, Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, c. 31, sy. 3, ss. 417–427, 2025.
ISNAD İşgören, Melike. “Kozalak Sapı Tozu Kullanarak Sulu çözeltilerden Telon Blue Boyası Adsorpsiyonu: İzoterm, Kinetik Modelleri Ve Adsorpsiyon ısısı”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 31/3 (Haziran 2025), 417-427.
JAMA İşgören M. Kozalak Sapı tozu kullanarak sulu çözeltilerden Telon Blue Boyası adsorpsiyonu: İzoterm, Kinetik modelleri ve adsorpsiyon ısısı. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2025;31:417–427.
MLA İşgören, Melike. “Kozalak Sapı Tozu Kullanarak Sulu çözeltilerden Telon Blue Boyası Adsorpsiyonu: İzoterm, Kinetik Modelleri Ve Adsorpsiyon ısısı”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, c. 31, sy. 3, 2025, ss. 417-2.
Vancouver İşgören M. Kozalak Sapı tozu kullanarak sulu çözeltilerden Telon Blue Boyası adsorpsiyonu: İzoterm, Kinetik modelleri ve adsorpsiyon ısısı. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2025;31(3):417-2.





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